Catalytic enantioselective aldol reactions

被引：241

作者：

Yamashita, Yasuhiro ^{[1
]}

Yasukawa, Tomohiro ^{[1
]}

Yoo, Woo-Jin ^{[1
]}

Kitanosono, Taku ^{[1
]}

Kobayashi, Shu ^{[1
]}

机构：

[1] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo, Japan

来源：

CHEMICAL SOCIETY REVIEWS | 2018年 / 47卷 / 12期

基金：

日本学术振兴会;

关键词：

DIRECT ASYMMETRIC ALDOL; SILYL ENOL ETHERS; LEWIS-ACID CATALYSTS; CHIRAL FERROCENYLAMINE LIGANDS; SUPPORTED L-PROLINE; HETERO-DIELS-ALDER; BETA; GAMMA-UNSATURATED ALPHA-KETOESTERS; C(2)-SYMMETRIC COPPER(II) COMPLEXES; WATER-COMPATIBLE ORGANOCATALYSTS; QUATERNARY CARBON CENTERS;

D O I：

10.1039/c7cs00824d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent developments in catalytic asymmetric aldol reactions have been summarized. Enantioselective aldol reactions are important methods to synthesize beta-hydroxy carbonyl compounds in optical pure form, and as such, numerous successful chiral catalysts were designed and applied for asymmetric aldol reactions. This review article is organized under the categories of: (1) catalytic enantioselective aldol reactions of preformed enolates, (2) catalytic enantioselective direct-type aldol reactions using chiral metal catalysts, (3) catalytic enantioselective direct-type aldol reactions using organocatalysts, (4) catalytic enantioselective aldol reactions in aqueous media. Examples of the aldol reactions that employ simple carbonyl compounds will be also the focus of this review.

引用

页码：4388 / 4480

页数：93

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