Synthesis of a highly reactive heterocyclic reactant and its unusual photochemistry; Mechanistic and exploratory organic photochemistry

被引：6

作者：

Zimmerman, HE ^{[1
]}

Pushechnikov, A ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 21期

关键词：

D O I：

10.1021/ol048438h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(GRAPHICS) A unique new set of reactions has been observed in heterocyclic photochemistry. 2-Methyl-4,4-diphenyl-3,4-dihydropyrimidin-1(2H)-one has been synthesized and its photochemistry investigated. This compound has been found to lead to a rearranged, dimeric product arising from a unique bond-scission process.

引用

页码：3779 / 3780

页数：2

共 5 条

[1] PHOTOCHEMICAL-REACTIONS .13. PHOTOCHEMICAL REACTIVITY OF ALPHA,BETA-UNSATURATED DELTA-LACTAMS - SYNTHESIS OF SECO-STEROIDS [J].