A heptanuclear Fe(II)-Fe(III)6 system with twelve unpaired electrons

被引：57

作者：

Gembicky, M

Boca, R ^{[1
]}

Renz, F

机构：

[1] Slovak Univ Technol Bratislava, Dept Inorgan Chem, SK-81238 Bratislava, Slovakia

[2] Johannes Gutenberg Univ Mainz, Inst Inorgan & Analyt Chem, D-55099 Mainz, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 11期

关键词：

heptanuclear iron complex; high-spin molecule; iron(II)-iron(III) mixed valence; magnetic susceptibility; Mossbauer spectra;

D O I：

10.1016/S1387-7003(00)00160-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pentadentate ligand (LH2)-L-5 = saldptn = N,N'-bis(1-hydroxy-2-benzyliden)-1,7-diamino-4-azaheptane has been prepared by a Schiff base condensation between 1,7-diamino-4-azaheptane and the corresponding salicyaldehyde. Its complexation with Fe(III) gave the high-spin (S = 5/2) complex of [Fe-III(L-5)Cl]. This precursor was combined with [Fe(CN)(6)](4-) and a blue heptanuclear complex [Fe-II{(CN)Fe-III(L-5)}(6)]Cl-2 resulted. This system belongs to the class of high-spin molecules possessing twelve unpaired electrons (S = 6) as proven by the magnetic susceptibility measurements and Mossbauer spectra. (C) 2000 Elsevier Science S.A. All rights reserved.

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页码：662 / 665

页数：4

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