Experimental evidence for the formation of HXeCCH: The first hydrocarbon with an inserted rare-gas atom

被引：138

作者：

Feldman, VI

Sukhov, FF

Orlov, AY

Tyulpina, IV

机构：

[1] Karpov Inst Phys Chem, Moscow 105064, Russia

[2] RAS, Inst Synthet Polymer Mat, Moscow 117393, Russia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 16期

关键词：

D O I：

10.1021/ja034585j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Combined FTIR and EPR studies of acetylene irradiated with fast electrons in a solid xenon matrix provide experimental evidence for the formation of HXeCCH, a novel-type organic molecule with an inserted rare-gas atom. The new species resulting from the reaction of H atoms with CCH radicals in xenon was characterized by an intense IR absorption at 1486.0 cm-1 corresponding to Xe-H stretching. Copyright © 2003 American Chemical Society.

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页码：4698 / 4699

页数：2

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