Band structure and electrical properties of Gd-doped HfO2 high k gate dielectric

被引:69
作者
Xiong, Yuhua [1 ]
Tu, Hailing [1 ]
Du, Jun [1 ]
Ji, Mei [1 ]
Zhang, Xinqiang [1 ]
Wang, Lei [1 ]
机构
[1] Gen Res Inst NonFerrous Met, Adv Elect Mat Inst, Beijing 100088, Peoples R China
基金
中国国家自然科学基金;
关键词
capacitance; conduction bands; current density; doping; energy gap; gadolinium; hafnium compounds; high-k dielectric thin films; leakage currents; noncrystalline structure; permittivity; RARE-EARTH-OXIDE; ELECTRONIC-STRUCTURE; THIN-FILMS; TRANSISTORS;
D O I
10.1063/1.3460277
中图分类号
O59 [应用物理学];
学科分类号
摘要
Effects of Gd doping on band gap, band offset, oxygen vacancies, and electrical properties of amorphous HfO2 film have been studied. The results show that Gd incorporation helps increase band gap, conduction band offset and conduction band minimum, and reduce oxygen vacancies simultaneously. Kept at the same physical thickness of 5 nm, Gd-doped HfO2 gate dielectric has a leakage current density of 9.0x10(-4) A/cm(2) at 1 V gate voltage, one and a half orders of magnitude lower than that of the pure HfO2. Gd doping also enhances the dielectric constant. The capacitance equivalent thicknesses of 0.98 nm and 0.81 nm for HfO2 and Gd-doped HfO2 films, respectively, have been obtained. (C) 2010 American Institute of Physics. [doi:10.1063/1.3460277]
引用
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页数:3
相关论文
共 26 条
[1]   Optical characterization of HfO2 thin films grown by atomic layer deposition [J].
Aarik, J ;
Mändar, H ;
Kirm, M ;
Pung, L .
THIN SOLID FILMS, 2004, 466 (1-2) :41-47
[2]   Band alignment between (100)Si and complex rare earth/transition metal oxides [J].
Afanas'ev, VV ;
Stesmans, A ;
Zhao, C ;
Caymax, M ;
Heeg, T ;
Schubert, J ;
Jia, Y ;
Schlom, DG ;
Lucovsky, G .
APPLIED PHYSICS LETTERS, 2004, 85 (24) :5917-5919
[3]   Structural and dielectric properties of amorphous ZrO2 and HfO2 [J].
Ceresoli, Davide ;
Vanderbilt, David .
PHYSICAL REVIEW B, 2006, 74 (12)
[4]   Permittivity enhancement of hafnium dioxide high-κ films by cerium doping [J].
Chalker, P. R. ;
Werner, M. ;
Romani, S. ;
Potter, R. J. ;
Black, K. ;
Aspinall, H. C. ;
Jones, A. C. ;
Zhao, C. Z. ;
Taylor, S. ;
Heys, P. N. .
APPLIED PHYSICS LETTERS, 2008, 93 (18)
[5]   Influence of oxygen vacancies on the electronic structure of HfO2 films [J].
Cho, Deok-Yong ;
Lee, Jae-Min ;
Oh, S. -J. ;
Jang, Hoyoung ;
Kim, J. -Y. ;
Park, J. -H. ;
Tanaka, A. .
PHYSICAL REVIEW B, 2007, 76 (16)
[6]   Influence of oxygen vacancies on the dielectric properties of hafnia: First-principles calculations [J].
Cockayne, Eric .
PHYSICAL REVIEW B, 2007, 75 (09)
[7]  
FANCIULLI M, 2007, RARE EARTH OXIDE FIL, P285
[8]   Higher permittivity rare earth doped HfO2 for sub-45-nm metal-insulator-semiconductor devices [J].
Govindarajan, S. ;
Boescke, T. S. ;
Sivasubramani, P. ;
Kirsch, P. D. ;
Lee, B. H. ;
Tseng, H.-H. ;
Jammy, R. ;
Schroeder, U. ;
Ramanathan, S. ;
Gnade, B. E. .
APPLIED PHYSICS LETTERS, 2007, 91 (06)
[9]   Electronic structure analysis of Zr silicate and Hf silicate films by using spatially resolved valence electron energy-loss spectroscopy [J].
Ikarashi, N ;
Manabe, K .
JOURNAL OF APPLIED PHYSICS, 2003, 94 (01) :480-486
[10]   The n-type Gd-doped HfO2 to silicon heterojunction diode [J].
Ketsman, I. ;
Losovyj, Y. B. ;
Sokolov, A. ;
Tang, J. ;
Wang, Z. ;
Belashchenko, K. D. ;
Dowben, P. A. .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2007, 89 (02) :489-492