Homoleptic and heteroleptic bis-NHC Cu(I) complexes as carbene transfer reagents

被引：25

作者：

Santoro, Orlando ^{[1
]}

Lazreg, Faima ^{[1
]}

Cordes, David B. ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Cazin, Catherine S. J. ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 12期

基金：

英国工程与自然科学研究理事会;

关键词：

N-HETEROCYCLIC CARBENE; REACTIVITY;

D O I：

10.1039/c6dt00595k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Homo- and heteroleptic bis-NHC copper(I) complexes have been efficiently used as carbene transfer reagents to Au and Pd. The simple and straightforward procedure allows for the synthesis of well-known gold complexes as well as novel cationic bis-NHC Pd(II) species.

引用

页码：4970 / 4973

页数：4

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