Carboxylation of Phenols with CO2 at Atmospheric Pressure

被引：71

作者：

Luo, Junfei ^{[1
,2
]}

Preciado, Sara ^{[2
]}

Xie, Pan ^{[1
]}

Larrosa, Igor ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Oxford Rd, Manchester M13 9PL, Lancs, England

[2] Queen Mary Univ London, Sch Biol & Chem Sci, Joseph Priestley Bldg,Mile End Rd, London E1 4NS, England

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 20期

基金：

欧洲研究理事会; 英国工程与自然科学研究理事会;

关键词：

carbon dioxide; Kolbe-Schmitt reaction; phenols; salicylic acids; synthetic methods; KOLBE-SCHMITT REACTION; CATALYZED DIRECT CARBOXYLATION; CARBENE COPPER(I) COMPLEXES; C-H CARBOXYLATION; CARBON-DIOXIDE; SALICYLIC-ACID; ALKENYLBORONIC ESTERS; MECHANISM; DERIVATIVES; BONDS;

D O I：

10.1002/chem.201601114

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A convenient and efficient method for the ortho-carboxylation of phenols under atmospheric CO2 pressure has been developed. This method provides an alternative to the previously reported Kolbe-Schmitt method, which requires very high pressures of CO2. The addition of a trisubstituted phenol has proved essential for the successful carboxylation of phenols with CO2 at standard atmospheric pressure, allowing the efficient preparation of a broad variety of salicylic acids.

引用

页码：6798 / 6802

页数：5

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