Conversion of nonporous helical cadmium organic framework to a porous form

被引：70

作者：

Gu, Zhi-Gang ^{[1
]}

Cai, Yue-Peng ^{[1
]}

Fang, Hua-Cai ^{[1
]}

Zhou, Zheng-Yuan ^{[1
]}

Thallapally, Praveen K. ^{[2
]}

Tian, Jian ^{[2
]}

Liu, Jun ^{[2
]}

Exarhos, Gregory J. ^{[2
]}

机构：

[1] S China Normal Univ, Sch Chem & Environm,Minist Educ, Key Lab Technol Elect Energy Storage & Power Gene, Engn Res Ctr Mat & Technol Elect EnergyStorage, Guangzhou 510006, Guangdong, Peoples R China

[2] Pacific NW Natl Lab, Energy & Environm Directorate, Richland, WA 99352 USA

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 29期

基金：

中国国家自然科学基金;

关键词：

SINGLE-CRYSTAL TRANSFORMATION; COORDINATION POLYMERS; SORPTION PROPERTIES; CARBON; SEPARATION; MOLECULES; CHEMISTRY; LAYER; CONSTRUCTION; NANOTUBES;

D O I：

10.1039/c0cc01042a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel cadmium-organic frameworks containing achiral helical nanotubular channels, [Cd(HImDC)(S)](n) (S = Im(1) and Py(2)), have been synthesized and characterized using single crystal X-ray diffraction, in which 1 converts to 2 upon refluxing 1 in pyridine solution with noticeable porosity and hydrogen uptake at medium pressure.

引用

页码：5373 / 5375

页数：3

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