Superior thoroughly mesoporous ternary hybrid photocatalysts of TiO2/WO3/g-C3N4 nanofibers for visible-light-driven hydrogen evolution

被引:115
作者
Hou, Huilin [1 ]
Gao, Fengmei [1 ]
Wang, Lin [1 ]
Shang, Minghui [1 ]
Yang, Zuobao [1 ]
Zheng, Jinju [1 ]
Yang, Weiyou [1 ]
机构
[1] Ningbo Univ Technol, Inst Mat, Ningbo 315016, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
ELECTRON-TRANSFER; TIO2; NANOFIBERS; WATER; ARRAYS; CDS; NANOSTRUCTURES; IRRADIATION; PERFORMANCE; DESIGN; RATIOS;
D O I
10.1039/c6ta02307j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel and highly efficient visible-light-driven photocatalyst with robust stability, made up of thoroughly mesoporous TiO2/WO3/g-C3N4 ternary hybrid nanofibers, has been fabricated through a foaming-assisted electrospinning process followed by a solution dipping process. These fibers, without the assistance of a noble metal, yielded a high visible-light-driven photocatalytic H-2 release rate of similar to 286.6 mu mol h(-1), which was 65 times greater than that displayed by the pure TiO2 counterparts.
引用
收藏
页码:6276 / 6281
页数:6
相关论文
共 46 条
[11]   Electrospinning 3C-SiC Mesoporous Fibers with High Purities and Well-Controlled Structures [J].
Hou, Huilin ;
Gao, Fengmei ;
Wei, Guodong ;
Wang, Mingfang ;
Zheng, Jinju ;
Tang, Bin ;
Yang, Weiyou .
CRYSTAL GROWTH & DESIGN, 2012, 12 (01) :536-539
[12]   Effective visible light-activated B-Doped and B,N-Codoped TiO2 photocatalysts [J].
In, Suil ;
Orlov, Alexander ;
Berg, Regina ;
Garcia, Felipe ;
Pedrosa-Jimenez, Sergio ;
Tikhov, Mintcho S. ;
Wright, Dominic S. ;
Lambert, Richard M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (45) :13790-+
[13]   Constructing graphite-like carbon nitride modified hierarchical yolk-shell TiO2 spheres for water pollution treatment and hydrogen production [J].
Jiang, Zhifeng ;
Zhu, Chengzhang ;
Wan, Weiming ;
Qian, Kun ;
Xie, Jimin .
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (05) :1806-1818
[14]   Z-scheme photocatalytic hydrogen production over WO3/g-C3N4 composite photocatalysts [J].
Katsumata, Hideyuki ;
Tachi, Yusuke ;
Suzuki, Tohru ;
Kaneco, Satoshi .
RSC ADVANCES, 2014, 4 (41) :21405-21409
[15]   Enhanced Photocatalytic and Photoelectrochemical Activity in the Ternary Hybrid of CdS/TiO2/WO3 through the Cascadal Electron Transfer [J].
Kim, Hyoung-il ;
Kim, Jungwon ;
Kim, Wooyul ;
Choi, Wonyong .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (19) :9797-9805
[16]   Heterogeneous photocatalyst materials for water splitting [J].
Kudo, Akihiko ;
Miseki, Yugo .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :253-278
[17]   Enhanced photochemical response of TiO2/CdSe heterostructured nanowires [J].
Lee, Jung-Chul ;
Kim, Tae Geun ;
Choi, Heon-Jin ;
Sung, Yun-Mo .
CRYSTAL GROWTH & DESIGN, 2007, 7 (12) :2588-2593
[18]   Novel-structured electrospun TiO2/CuO composite nanofibers for high efficient photocatalytic cogeneration of clean water and energy from dye wastewater [J].
Lee, Siew Siang ;
Bai, Hongwei ;
Liu, Zhaoyang ;
Sun, Darren Delai .
WATER RESEARCH, 2013, 47 (12) :4059-4073
[19]   A New Visible-Light Photocatalyst: CdS Quantum Dots Embedded Mesoporous TiO2 [J].
Li, Gui-Sheng ;
Zhang, Die-Qing ;
Yu, Jimmy C. .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (18) :7079-7085
[20]   Au-ZnO Hybrid Nanopyramids and Their Photocatalytic Properties [J].
Li, Peng ;
Wei, Zhe ;
Wu, Tong ;
Peng, Qing ;
Li, Yadong .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (15) :5660-5663