Platform Chemicals via Zeolite-Catalyzed Fast Pyrolysis of Glucose

被引：10

作者：

Puertolas, Begona ^{[1
]}

Imtiaz, Qasim ^{[2
]}

Muller, Christoph R. ^{[2
]}

Perez-Ramirez, Javier ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, Inst Chem & Bioengn, Dept Chem & Appl Biosci, Vladimir Prelog Weg 1, CH-8093 Zurich, Switzerland

[2] Swiss Fed Inst Technol, Dept Mech & Proc Engn, Lab Energy Sci & Engn, Leonhardstr 21, CH-8092 Zurich, Switzerland

来源：

CHEMCATCHEM | 2017年 / 9卷 / 09期

关键词：

biomass; Lewis acids; platform chemicals; pyrolysis; zeolites; SOLID ACID CATALYSTS; BIOMASS; DEHYDRATION; CONVERSION; FRUCTOSE; HYDROCARBONS; CELLULOSE;

D O I：

10.1002/cctc.201601052

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Furan derivatives, such as 5-hydroxymethylfurfural (HMF) and furfural, obtained from renewable feedstocks are sustainable alternatives to petroleum-based building blocks for the manufacture of chemical products. This study shows for the first time the applicability of the catalytic fast pyrolysis (CFP) of glucose over tailored zeolites for the production of HMF and furfural. In particular, we demonstrate that Lewis-acid-containing faujasite zeolites attained by alkali metal-cation exchange exhibit combined yields to these platform molecules of 17%. Despite the fact that further research is required on the process assessment at a larger scale and under more realistic conditions, CFP has potential for the production of biomass-derived commodity chemicals.

引用

页码：1579 / 1582

页数：4

共 40 条

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