Organocatalytic hydroborylation promoted by N-heterocyclic olefins

被引：28
|
作者：
Hering-Junghans, Christian [1 ]
Watson, Ian C. [1 ]
Ferguson, Michael J. [1 ]
McDonald, Robert [1 ]
Rivard, Eric [1 ]
机构：
[1] Univ Alberta, Dept Chem, 11227 Saskatchewan Dr, Edmonton, AB T6G 2G2, Canada
来源：
DALTON TRANSACTIONS | 2017年 / 46卷 / 22期
基金：
加拿大创新基金会; 加拿大自然科学与工程研究理事会;
关键词：
CARBONYL-COMPOUNDS; CATALYZED HYDROBORATION; LEWIS PAIRS; ACTIVATION; COMPLEXES; PHOSPHINE; KETONES; CO2; DERIVATIVES; CONVERSION;
D O I：
10.1039/c7dt01303e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New complexes containing N-heterocyclic vinylene-stabilized [B2H5](+) fragments were prepared, and surprisingly it was found that the precursor N-heterocyclic olefins (NHOs) could promote the mild (room temperature) catalytic hydroborylation of ketones and aldehydes. This finding represents an important addition to the burgeoning field of non-metal mediated catalysis.
引用
收藏
页码：7150 / 7153
页数：4
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