High Precision Droplet-Based Microfluidic Determination of Americium(III) and Lanthanide(III) Solvent Extraction Separation Kinetics

被引：38
作者：
Launiere, C. A. [1 ]
Gelis, A. V. [1 ]
机构：
[1] Argonne Natl Lab, Nucl Engn Div, Lemont, IL 60439 USA
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2016年 / 55卷 / 07期
关键词：
INTERFACIAL MASS-TRANSFER; LIQUID-LIQUID-EXTRACTION; DODECANE-NACL; DIOXOURANIUM(VI); MECHANISM; SYSTEM; AREA; ACID; FLOW;
D O I：
10.1021/acs.iecr.5b04691
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A new method for studying solvent extraction kinetics has been applied for measuring americium and lanthanide extraction rate constants. This droplet-based microfluidic method uses commercially available components and provides rapid, high throughput and accurate determination of absolute interfacial mass transfer rate constants. Reported for the first time are americium extraction rates relevant to TALSPEAK-type process conditions, including the americium and lanthanide rate dependencies on pH and extractant power.
引用
收藏
页码：2272 / 2276
页数：5
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