Catalytic liquid-phase phenol oxidation over metal oxides and molecular sieves. Reaction kinetics and mechanism

被引：0

作者：

Pintar, A ^{[1
]}

Bercic, G ^{[1
]}

Batista, J ^{[1
]}

Levec, J ^{[1
]}

机构：

[1] Natl Inst Chem, Lab Catalysis & Chem React Engn, SI-1001 Ljubljana, Slovenia

来源：

3RD WORLD CONGRESS ON OXIDATION CATALYSIS | 1997年 / 110卷

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Oxidation of aqueous phenol solutions was studied over various catalysts in a semibatch slurry and continuous-flow fixed-bed reactors at temperatures up to 463 K and pressures slightly above atmospheric. The results show that due to a complex consecutive-parallel reaction pathway and a heterogeneous-homogeneous free-radical mechanism both kinetics and reaction selectivity are strongly dependent on the type of reactor used. Although the catalysts employed were found to be active in converting aqueous phenol solutions to nontoxic compounds, neither metal oxides nor zeolites were stable at the reaction conditions.

引用

页码：633 / 642

页数：10

共 50 条

[41] Liquid phase selective oxidation of alcohols over modified molecular sieves [J].

Srinivas, N ;

Rani, VR ;

Kishan, MR ;

Kulkarni, SJ ;

Raghavan, KV .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 172 (1-2) :187-191

[42] EFFECT OF SOME FACTORS ON AIR OXIDATION KINETICS OF BENZENE AND PHENOL IN LIQUID-PHASE [J].

SHABOLDO, PI ;

SUKHAREV, BN ;

PROKURYA.VA ;

POTEKHIN, VM .

ZHURNAL PRIKLADNOI KHIMII, 1972, 45 (06) :1324-+

[43] Phenol synthesis by liquid-phase oxidation of benzene with molecular oxygen over iron-heteropoly acid [J].

Seo, YJ ;

Mukai, Y ;

Tagawa, T ;

Goto, S .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 120 (1-3) :149-154

[44] CATALYTIC-OXIDATION OF HYDROCARBONS IN LIQUID-PHASE - INVESTIGATIONS ON TOLUENE OXIDATION REACTION [J].

RYBAK, W ;

KOWALIK, Z ;

ZIOLKOWS.JJ .

PRZEMYSL CHEMICZNY, 1974, 53 (02) :87-90

[45] KINETICS OF P-XYLENE LIQUID-PHASE CATALYTIC-OXIDATION [J].

CAO, GM ;

SERVIDA, A ;

PISU, M ;

MORBIDELLI, M .

AICHE JOURNAL, 1994, 40 (07) :1156-1166

[46] Kinetics of the liquid-phase catalytic oxidation of toluene to benzoic acid by air [J].

Zhang, Nan ;

Liu, Jiansong ;

Chen, Jizhong .

Huaxue Fanying Gongcheng Yu Gongyi/Chemical Reaction Engineering and Technology, 2008, 24 (01) :18-23

[47] KINETICS AND REACTION MECHANISM OF ACETALDEHYDE OXIDATION IN LIQUID PHASE [J].

GUT, G ;

WIRTH, M .

CHIMIA, 1968, 22 (11) :425-&

[48] CHANGES IN THE MECHANISM OF THE REACTION OF LIQUID-PHASE OXIDATION OF TOLUENE DERIVATIVES [J].

SHCHERBINA, FF .

UKRAINSKII KHIMICHESKII ZHURNAL, 1987, 53 (01) :89-93

[49] Influence of the conditions of the liquid-phase oxidation of hexadecane on the reaction mechanism [J].

Oganesova, EY ;

Bordubanova, EG ;

Popova, ZV ;

Bakunin, VN ;

Kuz'mina, GN ;

Parenago, OP .

PETROLEUM CHEMISTRY, 2004, 44 (02) :99-105

[50] KINETICS OF THE LIQUID-PHASE HYDROGENATION OF PHENOL TO CYCLOHEXANOL OVER A NICKEL CHROMIUM CATALYST [J].

PALKIN, PN ;

KONYUKHOV, VY ;

GOSTIKIN, VP ;

TEMKIN, MI .

KINETICS AND CATALYSIS, 1983, 24 (06) :1181-1184

← 1 2 3 4 5 →