Preferential solvation in mixed solvents. 16. Mixtures of N,N-dimethylformamide or propylene carbonate with organic solvents

被引:4
|
作者
Marcus, Yizhak [1 ]
机构
[1] Hebrew Univ Jerusalem, Inst Chem, IL-91904 Jerusalem, Israel
来源
JOURNAL OF CHEMICAL THERMODYNAMICS | 2020年 / 140卷 / 140期
关键词
N; N-dimethylformamide; Propylene carbonate; Binary liquid mixtures; Preferential solvation; Self-association; EXCESS GIBBS ENERGIES; BINARY-MIXTURES; MOLAR VOLUMES; ACETONITRILE; ENTHALPY; WATER;
D O I
10.1016/j.jct.2019.105903
中图分类号
O414.1 [热力学];
学科分类号
摘要
The preferential solvation parameters for the self-association and the mutual association of each of N,N-dimethylformamide and propylene carbonate with a co-solvent in their binary mixtures as well as the self-association of each of these components at infinite dilution in the other component as solvent have been calculated from previously reported experimental data, using the inverse Kirkwood-Buff integrals approach. (C) 2019 Elsevier Ltd.
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页数:4
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