Hydrothermal Synthesis, Crystal Structure and Photoluminescence of a Novel Three-Dimensional Zinc(II) Complex: [Zn2(OH)(pyim)(BIPA)]n

被引：0

作者：

Liu Guang-Xiang ^{[1
]}

Xu Yu-Yong ^{[1
]}

Huang Rong-Yi ^{[1
]}

Ren Xiao-Ming ^{[1
]}

机构：

[1] Anqing Normal Univ, Sch Chem & Chem Engn, Anhui Key Lab Funct Coordinat Cpds, Anqing 246003, Anhui, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 26卷 / 08期

关键词：

Zinc(II) complex; crystal structure; multicarboxylate ligand; luminescence; COORDINATION POLYMERS; LIGANDS SYNTHESES; BUILDING-BLOCKS; METAL; DESIGN; SEPARATION; CADMIUM(II);

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrothermal reaction between 5-bromoisophthalic acid (H(2)BIPA) and Zn(NO3)(2)center dot 6H(2)O at the presence of the second ligand of 2-(2-pyridyl)imidazole (Hpyim) yields a new 3D metal-organic coordination polymer [Zn-2(OH)(pyim)(BIPA)](n) (1), which has been characterized by single-crystal X-ray diffraction, elemental analysis, IR spectrum and thermal analysis. Complex 1 presents an alpha-Po net with 4(12)6(3) topology constructed from tetranuclear clusters and displays strong luminescent emission at room temperature. CCDC: 763940.

引用

页码：1477 / 1481

页数：5

共 26 条

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