Metallic vanadium trioxide intercalated with phase transformation for advanced aqueous zinc-ion batteries

被引：43
作者：
Hu, Kang [1 ]
Jin, Danqing [1 ]
Zhang, Yao [1 ]
Ke, Longwei [1 ]
Shang, Huan [1 ]
Yan, Yan [1 ]
Lin, Huijuan [1 ]
Rui, Kun [1 ]
Zhu, Jixin [1 ]
机构：
[1] Nanjing Tech Univ, Inst Adv Mat IAM, Nanjing 211816, Jiangsu, Peoples R China
来源：
JOURNAL OF ENERGY CHEMISTRY | 2021年 / 61卷
基金：
中国国家自然科学基金;
关键词：
Metallic vanadium trioxide; Intercalated reaction; Cathode; Aqueous zinc-ion batteries; Phase transformation; HIGH-CAPACITY; CATHODE; PERFORMANCE; VANADATE; LIFE; V2O5;
D O I：
10.1016/j.jechem.2021.02.014
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Aqueous zinc-ion batteries have broad application prospects due to the eco-friendliness, cost-economy and high safety. However, the scarcity of high-performance cathodes with outstanding rate capability and long lifespan has affected their development. Herein, we report a metallic vanadium trioxide material intercalated with phase transformation as cathode applied in aqueous zinc-ion batteries. It offers satisfactory electrochemical performances with a high specific capacity (435 mAh g(-1) at 0.5 A g(-1)), decent power density (5.23 kW kg(-1)) and desired energy density (331 Wh kg(-1)), as well as good cyclability. The superior performance originates from the stable structure and fast Zn2+ diffusion, enabled by the pre-intercalation of Zn2+ and water molecules. (C) 2021 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.
引用
收藏
页码：594 / 601
页数：8
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