Thermophysical and sonochemical behavior of binary mixtures of hexan-1-ol with halohydrocarbons at 303.15 K

被引：5

作者：

Bhatia, Subhash C. ^{[1
]}

Bhatia, Rachna ^{[1
]}

Dubey, Gyan P. ^{[1
]}

机构：

[1] Kurukshetra Univ, Dept Chem, Kurukshetra 136119, Haryana, India

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2010年 / 152卷 / 1-3期

关键词：

Hexan-1-ol+ halohydrocarbons; Excess molar volumes; Schaaffs' collision factor theory; Thermoacoustical parameters; Prigogine-Flory-Patterson theory; EXCESS MOLAR VOLUMES; INTERMOLECULAR FREE-LENGTH; LIQUID-MIXTURES; ISENTROPIC COMPRESSIBILITIES; REFRACTIVE-INDEX; MOLECULAR-INTERACTIONS; ADIABATIC COMPRESSIBILITIES; THERMODYNAMIC PROPERTIES; DIFFERENT TEMPERATURES; INTERNAL-PRESSURES;

D O I：

10.1016/j.molliq.2010.01.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Densities and ultrasonic velocities of binary mixtures of hexan-1-ol with 1,2-dichloroethane. 1,2-dibromoethane and 1,1,2,2-tetrachloroethene have been measured over the entire range of composition at 303.15 K at the atmospheric pressure. From these experimental data, the excess molar volumes, molar free volumes, molar isentropic compressibilities, limiting excess partial molar volumes and isentropic compressibilities, deviations in ultrasonic velocity, molecular radii, Rao's molar sound functions. parameters related to space-filling ability, Beyer's parameters of non-linearity, available volumes and intermolecular free lengths by three methods have been estimated The excess functions have been fitted to the Redlich-Kister polynomial functions and the results have been analyzed in terms of Nomoto's relation (N), Van Dad's relation (VD), Jacobson's free length theory (FLT). Schaaffs' collision factor theory (CFT), thermoacoustical parameters (TAP) and Prigogine-Flory-Patterson theory (PFP) (C) 2010 Elsevier B V All rights reserved

引用

页码：39 / 52

页数：14

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