Synthesis and characterization of two 3-D polymeric lanthanide complexes constructed from 1,2,4,5-benzenetetracarboxylic acid

被引:18
作者
Li, Xiaohu [1 ]
Wang, Yanping [1 ]
Ma, Zhiyun [1 ]
Zhang, Ronglan [1 ]
Zhao, Jianshe [1 ]
机构
[1] NW Univ Xian, Dept Chem, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ,Shaanxi Key Lab Phys Inorgan Chem, Xian 710069, Shaanxi, Peoples R China
基金
中国国家自然科学基金;
关键词
Coordination polymer; Hydrothermal method; Photoluminescence spectra; 1,2,4,5-Benzenetetracarboxylic acid; COORDINATION POLYMERS; STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURES; ORGANIC FRAMEWORK; MN-II; LIGANDS; NETWORK; SOLIDS; DESIGN;
D O I
10.1080/00958971003690439
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two 3-D porous coordination polymers, [Nd((a)btec)(2/4)((b)btec)(2/4)(H2O)](n) (1) and [NdYb((c)btec)(2/4)((d)btec)(2/4)((e)btec)(2/4)(H2O)(4)](n) (2), have been prepared by the hydrothermal method at 160 degrees C. Both complexes were characterized by elemental analyses, photoluminescence spectra, and single-crystal X-ray diffraction.
引用
收藏
页码:1029 / 1037
页数:9
相关论文
共 33 条
[1]   Syntheses and characterizations of three-dimensional channel-like polymeric lanthanide complexes constructed by 1,2,4,5-benzenetetracarboxylic acid [J].
Cao, R ;
Sun, DF ;
Liang, YC ;
Hong, MC ;
Tatsumi, K ;
Shi, Q .
INORGANIC CHEMISTRY, 2002, 41 (08) :2087-2094
[2]   Monomeric and polymeric copper(II) hexaaza macrocyclic complexes with btc anions (btc=1,2,4,5-benzenetetracarboxylic acid) [J].
Cho, J ;
Lough, AJ ;
Kim, JC .
INORGANICA CHIMICA ACTA, 2003, 342 :305-310
[3]   Molecular chromium(III)-lanthanide(III) compounds (Ln=La, Ce, Pr, Nd) with a polymeric, ladder-type architecture: A structural and magnetic study [J].
Decurtins, S ;
Gross, M ;
Schmalle, HW ;
Ferlay, S .
INORGANIC CHEMISTRY, 1998, 37 (10) :2443-2449
[4]   Luminescent Ln3+ nitrobenzoato complexes:: first examples of sensitization of green and red emission [J].
Dias, AD ;
Viswanathan, S .
CHEMICAL COMMUNICATIONS, 2004, (08) :1024-1025
[5]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472
[6]   Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].
Eddaoudi, M ;
Moler, DB ;
Li, HL ;
Chen, BL ;
Reineke, TM ;
O'Keeffe, M ;
Yaghi, OM .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330
[7]   Crystal engineering of NLO materials based on metal-organic coordination networks [J].
Evans, OR ;
Lin, WB .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522
[8]   USE OF HETEROMETAL COMBINATIONS TO CONSTRUCT VERY BARGE RING FRAMEWORKS - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE 36-MEMBERED RING COMPOUND [(NIND(4-PICOLYLPYRROLIDIN-2-ONE)(4)(NCS)(2)(NO3)(3))(N)] [J].
GOODGAME, DML ;
MENZER, S ;
ROSS, AT ;
WILLIAMS, DJ .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (22) :2605-2606
[9]   Diversity of linking modes by N,N'-p-phenylenedimethylenebis(pyridin-4-one) [p-XBP4] in the novel 'linked lantern' framework complex {[Nd-2(p-XBP4)(6)(H2O)(4)](p-XBP4)(H2O)(3)(ClO4)(6)}(n) [J].
Goodgame, DML ;
Menzer, S ;
Smith, AM ;
Williams, DJ .
CHEMICAL COMMUNICATIONS, 1997, (04) :339-340
[10]  
Hollingsworth MD, 2002, SCIENCE, V295, P2410