UV curing of organic-inorganic hybrid coating materials

被引:64
作者
Han, Yung-Hoe
Taylor, Alan
Mantle, Michael D.
Knowles, Kevin M.
机构
[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England
[2] TWI, Cambridge CB1 6AL, England
[3] Univ Cambridge, Dept Chem Engn, Cambridge CB2 3RA, England
关键词
organic-inorganic hybrid material; sol-gel; tetraethoxysilane (TEOS); 3-(trimethoxysilyl)propyl methacrylate (MPTMA); UV curing;
D O I
10.1007/s10971-007-1544-8
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The effect of UV-curing time on the mechanism of interaction between the various precursor phases in a novel sol-gel-derived organic-inorganic hybrid coating material and the resulting mechanical and thermal properties of this material when coated onto substrates in thin film form have been examined using a variety of chemical and physical characterisation methods. Microstructurally, the hybrid coating materials examined were all a single amorphous phase and were all optically transparent. The degree of interaction between the organic and inorganic phases, the scratch behaviour of the coating materials and the thermal stability of the coating materials were all found to depend strongly on the UV curing time. For the particular proportions of inorganic and organic components used to make up this hybrid coating material, an optimum UV curing time of 10 min under a UV intensity of 46.3 mW cm(-2) was found to produce transparent coatings which adhered well to the substrates and which were robust in scratch tests on aluminium and polycarbonate substrates and abrasion tests on polycarbonate substrates.
引用
收藏
页码:111 / 123
页数:13
相关论文
共 39 条
[1]  
BRAITHWAITE M, 1991, CHEM TECHNOLOGY UV E, V4, P125
[2]  
Brinker C.J., 1990, SOL GEL SCI
[3]   THE RELATIONSHIP BETWEEN HARDNESS AND SCRATCH ADHESION [J].
BURNETT, PJ ;
RICKERBY, DS .
THIN SOLID FILMS, 1987, 154 (1-2) :403-416
[4]   Effect of hydrogen bonding on the glass transition behavior of poly(acrylic acid)/silica hybrid materials prepared by sol-gel process [J].
Chan, CK ;
Chu, IM .
POLYMER, 2001, 42 (14) :6089-6093
[5]  
Chang TC, 2000, J POLYM SCI POL CHEM, V38, P1972, DOI 10.1002/(SICI)1099-0518(20000601)38:11<1972::AID-POLA60>3.0.CO
[6]  
2-5
[7]   Photoinitiated cationic polymerization of cycloaliphatic epoxide with siloxane or alkoxysilane functionalized polyol coatings [J].
Chen, JX ;
Soucek, MD .
EUROPEAN POLYMER JOURNAL, 2003, 39 (03) :505-520
[8]   Synthesis, characterization, thermal properties and flame retardance of novel phenolic resin/silica nanocomposites [J].
Chiang, CL ;
Ma, CCM .
POLYMER DEGRADATION AND STABILITY, 2004, 83 (02) :207-214
[9]   AN ORGANIC-INORGANIC SINGLE-PHASE COMPOSITE [J].
DAVID, IA ;
SCHERER, GW .
CHEMISTRY OF MATERIALS, 1995, 7 (10) :1957-1967
[10]   Organic-inorganic hybrid coatings for coil coating application based on polyesters and tetraethoxysilane [J].
Frings, S ;
Meinema, H ;
van Nostrum, C ;
van der Linde, R .
PROGRESS IN ORGANIC COATINGS, 1998, 33 (02) :126-130