Efficient degradation of toxic mixed dyes through peroxymonosulfate activation by copper/iron nanoparticles loaded on 3D carbon: Synthesis, characterizations, and mechanism

Exploitation of heterogeneous catalysts with high activity, stability and reusability gains increasing worldwide attention due to the tremendous demand for purification of dye wastewater. Copper/iron bimetallic catalysts have been proven to be powerful for persulfate activation to generate reactive radical species. Copper/iron nanoparticles loaded onto porous carbon (Cu/FeNPs@PC) was innovatively designed and used as catalyst for peroxymonosulfate (PMS) activation. Cu/FeNPs@PC manifests high catalytic activity for dye degradation over a wide pH range (4.0-10.0). Under conditions of 0.2 g/L catalyst, PMS 0.15 g/L and pH 4.8, nearly complete degradation (98.4%) of Rhodamine B occurs after 18 min. The rate constant is between 0.0946 and 0.1911 min(-1) depending on initial solution pH. Mixed dyes can be efficiently degraded verified by UV-vis spectra and color variation of dye solution. Cu/FeNPs@PC has good stability, magnetism, and reusability for recycling. A synergistic effect of promoting Cu2+/Cu+ and Fe3+/Fe2+ cycle is probability ascribed to the enhanced catalytic activity. The mechanism of catalytic degradation of dyes involves radical species (SO4-center dot & nbsp; and center dot OH) and non-radical pathways including O-1(2) and mediated electron transfer. This work provides insights into rational design of binary metal catalysts that apply to treatment of dye wastewater.