Polyol Synthesis of Pd/Ag Alloy Nanocrystalline

被引：9

作者：

Kim, Chang-Hyun ^{[1
]}

Lim, Jin-Sub ^{[1
]}

Choi, Moon-Bong ^{[1
]}

Kim, Jae-Kook ^{[1
]}

Yang, Hyuck-Soo ^{[2
]}

Song, Sun-Ju ^{[1
]}

机构：

[1] Chonnam Natl Univ, Dept Mat Sci & Engn, Kwangju 500757, South Korea

[2] Samsung Elect Co Ltd, Syst LSI Div, Gyeonggi 446711, South Korea

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2010年 / 157卷 / 07期

关键词：

crystallites; nanofabrication; nanoparticles; palladium alloys; particle size; scanning electron microscopy; silver alloys; solid solutions; surfactants; transmission electron microscopy; X-ray diffraction; HYDROGEN SEPARATION MEMBRANES; CERMET MEMBRANES; NANOPARTICLES; PERMEATION; PD; CONDUCTIVITY; PERMEABILITY; OPTIMIZATION; OXIDATION; REACTOR;

D O I：

10.1149/1.3414468

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A solid solution of Pd-Ag nanoparticles was synthesized by the conventional polyol process. Silver nitrate (AgNO(3), Aldrich), palladium(II) nitrate hydrate [Pd(NO(3))(2)center dot xH(2)O, Aldrich], and ethylene glycol were used as the starting materials. Ethylene glycol was used as the surfactant for the solvent and reductant. Water was used to ensure that the reduction potentials of the two metals remained very similar in the aqueous solution. The obtained alloy nanopowder sample was characterized by X-ray diffraction (XRD). The obtained XRD pattern was refined using the Full-Prof program according to the Rietveld method and the mean crystallite sizes were estimated using the Scherrer equation. The quantitative atomic percentage across the nanoparticles was determined by using scanning transmission electron microscopy images to confirm the formation of the Pd/Ag alloy nanopowder. (C) 2010 The Electrochemical Society. [DOI: 10.1149/1.3414468] All rights reserved.

引用

页码：E107 / E110

页数：4

共 29 条

[1] Microwave Synthesis of Bimetallic Nanoalloys and CO Oxidation on Ceria-Supported Nanoalloys [J].

Abdelsayed, Victor ;

Aljarash, Ahlam ;

El-Shall, M. Samy ;

Al Othman, Zeid A. ;

Alghamdi, Ahmed H. .

CHEMISTRY OF MATERIALS, 2009, 21 (13) :2825-2834

[2] Hydrogen separation by dense cermet membranes [J].

Balachandran, U ;

Lee, TH ;

Chen, L ;

Song, SJ ;

Picciolo, JJ ;

Dorris, SE .

FUEL, 2006, 85 (02) :150-155

[3] Chemical diffusivity and ionic conductivity of GdBaCo2O5+δ [J].

Choi, M. -B. ;

Jeon, S. -Y. ;

Lee, J. -S. ;

Hwang, H. -J. ;

Song, S. -J. .

JOURNAL OF POWER SOURCES, 2010, 195 (04) :1059-1064

[4] Optimization of autothermal reactor for maximum hydrogen production [J].

Hagh, BF .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2003, 28 (12) :1369-1377

[5]

HAMAKAWA S, 2002, SOLID STATE IONICS, V71, P267

[6] Sn0.9In0.1P2O7-based organic/inorganic composite membranes application to intermediate-temperature fuel cells [J].

Heo, Pilwon ;

Nagao, Masahiro ;

Kamiya, Toshio ;

Sano, Mitsuru ;

Tomita, Atsuko ;

Hibino, Takashi .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (01) :B63-B67

[7] TECHNOLOGICAL CHALLENGES IN THE APPLICATION OF PROTON CONDUCTING CERAMICS [J].

IWAHARA, H .

SOLID STATE IONICS, 1995, 77 :289-298

[8] On the development of proton conducting materials for technological applications [J].

Kreuer, KD .

SOLID STATE IONICS, 1997, 97 (1-4) :1-15

[9] Extraction and production of hydrogen using high-temperature proton conductor [J].

Matsumoto, H ;

Okubo, M ;

Hamajima, S ;

Katahira, K ;

Iwahara, H .

SOLID STATE IONICS, 2002, 152 :715-720

[10] Mixed hydrogen ion-electronic conductors for hydrogen permeable membranes [J].

Norby, T ;

Larring, Y .

SOLID STATE IONICS, 2000, 136 (136-137) :139-148

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