Conversion of chemical reaction energy into useful work in the van't Hoff equilibrium box

被引：9

作者：

Bazhin, N. M. ^{[1
]}

Parmon, V. N.

机构：

[1] Novosibirsk State Univ, Inst Chem Kinet & Combust, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

JOURNAL OF CHEMICAL EDUCATION | 2007年 / 84卷 / 06期

关键词：

D O I：

10.1021/ed084p1053

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The production of useful work by means of the ideal "van't Hoff equilibrium box" is considered in detail. It is shown that useful work arises according to the scheme "reaction energy → heat → useful work" without violation of the second law of thermodynamics, even at constant temperature, using the heat evolved by a reaction. Van't Hoff equilibrium box divided in two parts can simultaneously produce heat (in volume 100% from theoretical one) and useful work (in volume 100% from theoretical one) without violation of the first law of thermodynamics.

引用

页码：1053 / 1055

页数：3