Thirty Years of (TMS)3SiH: A Milestone in Radical-Based Synthetic Chemistry

被引：252

作者：

Chatgilialoglu, Chryssostomos ^{[1
]}

Ferreri, Carla ^{[1
]}

Landais, Yannick ^{[2
]}

Timokhin, Vitaliy I. ^{[3
]}

机构：

[1] CNR, ISOF, Via P Gobetti 101, I-40129 Bologna, Italy

[2] Univ Bordeaux, Inst Mol Sci, CNRS, UMR 5255, 351 Cours Liberat, F-33405 Talence, France

[3] Univ Wisconsin Madison, Dept Biochem, 1552 Univ Ave, Madison, WI 53726 USA

来源：

CHEMICAL REVIEWS | 2018年 / 118卷 / 14期

关键词：

HYDROGEN-TERMINATED SILICON; SELF-DIRECTED GROWTH; CARBON-CENTERED RADICALS; CONVERGENT TOTAL-SYNTHESIS; VISIBLE-LIGHT; ORGANIC MONOLAYERS; STEREOSELECTIVE-SYNTHESIS; RATE CONSTANTS; CATIONIC-POLYMERIZATION; CYCLIZATION APPROACH;

D O I：

10.1021/acs.chemrev.8b00109

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review is an update on tris(trimethylsilyl)silane, TTMSS, in organic chemistry, focusing on the advancements of the past decade. The overview includes a wide range of chemical processes and synthetic strategies under different experimental conditions, including functional group insertion and transformations, as well as preparation of complex molecules, natural products, polymers, surfaces, and new materials. These results reveal how TTMSS has matured over the past 30 years, and they further establish its value as a free radical reagent with widespread academic and industrial applications.

引用

页码：6516 / 6572

页数：57

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