Organic dye photocatalyzed α-oxyamination through irradiation with visible light

被引：149

作者：

Liu, Hongjun ^{[1
]}

Feng, Wei ^{[1
]}

Kee, Choon Wee ^{[1
]}

Zhao, Yujun ^{[1
]}

Leow, Dasheng ^{[1
]}

Pan, Yuanhang ^{[1
]}

Tan, Choon-Hong ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

GREEN CHEMISTRY | 2010年 / 12卷 / 06期

关键词：

GREEN PHOTOCHEMISTRY; PHOTOREDOX CATALYSIS; FINE CHEMICALS; AQUEOUS-PHASE; CHEMISTRY; ORGANOCATALYSIS; PHOTOPHYSICS; ALKYLATION; ALDEHYDES; FLUORINE;

D O I：

10.1039/b924609f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rose Bengal, an organic dye, was used as a visible light photocatalyst to investigate novel alpha-oxyamination reactions between 1,3-dicarbonyl compounds and a free radical (TEMPO). Compounds that are difficult to obtain such as quaternary fluorinated compounds were synthesized using this method. This visible light photocatalytic reaction can also be performed in water.

引用

页码：953 / 956

页数：4

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