Recycling Powered by Release of Carbon Dioxide

被引：4

作者：

Nash, Anna Laurell ^{[1
]}

Widyan, Khalid ^{[1
]}

Moberg, Christina ^{[1
]}

机构：

[1] KTH Royal Inst Technol, Dept Chem, SE-10044 Stockholm, Sweden

来源：

CHEMCATCHEM | 2014年 / 6卷 / 12期

基金：

瑞典研究理事会;

关键词：

carbon dioxide; cyanoformate ester; enzymes; reaction mechanisms; titanium; SPONTANEOUS EMERGENCE; HOMOCHIRALITY; MODELS; ACID; ALDEHYDES; CHEMISTRY; SYSTEMS; CYCLES;

D O I：

10.1002/cctc.201402765

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In a cyclic process, fed with external chemical energy generated by the transformation of a compound with high chemical potential to carbon dioxide, the undesired enantiomer from a catalytic asymmetric reaction is continuously recycled to starting reagent. This minor enantiomer recycling is characterized by gradually increasing yields and product enantiomeric ratios. The requirements for maintaining a cyclic procedure are discussed; the necessity of a coupled exergonic process is demonstrated experimentally.

引用

页码：3314 / 3317

页数：4

共 18 条

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