Complexation with diol host compounds .25. Selective inclusion of benzenediol isomers by 1,1-bis(4-hydroxyphenyl)cyclohexane

被引：17

作者：

Caira, MR

Horne, A

Nassimbeni, LR

Toda, F

机构：

[1] UNIV CAPE TOWN,DEPT CHEM,ZA-7701 RONDEBOSCH,SOUTH AFRICA

[2] EHIME UNIV,FAC ENGN,DEPT APPL CHEM,MATSUYAMA,EHIME 790,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1997年 / 09期

关键词：

D O I：

10.1039/a701144j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title host compound includes all the isomers of the benzenediols. The structures with the p- and o-benzenediols have been elucidated and show that the clathrates are stabilised by hydrogen bonds, Competition experiments with the host in water suspension show that the para-isomer is preferentially enclathrated, Lattice energy calculations explain the results of the competition experiment.

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收藏

页码：1717 / 1720

页数：4

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