Picosecond optical Kerr ellipsometry determination of S1→Sn absorption spectra of xanthene dyes

被引：26

作者：

Delysse, S ^{[1
]}

Nunzi, JM

Scala-Valero, C

机构：

[1] DEIN SPE, Grp Composants Organ, LETI, CEA, F-91191 Gif Sur Yvette, France

[2] CE Saclay, CEA, DCC DPE SPL SCLO, F-91191 Gif Sur Yvette, France

来源：

APPLIED PHYSICS B-LASERS AND OPTICS | 1998年 / 66卷 / 04期

关键词：

D O I：

10.1007/s003400050416

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The excited-state absorption of rhodamine and pyronin dyes in ethanol is studied. The nonlinear optical Kerr ellipsometry pump-probe technique permits an absolute measurement of the differential absorption cross-section spectrum in the visible and near-infrared ranges. Energies and oscilla tor strengths of S-1 --> S-n transitions are evaluated with linear absorption and stimulated emission taken into account. A biexciton state is revealed within the stimulated emission band. Its binding energy (40 to 110 meV) and oscillator strength (0.3 to 0.6) are determined. Possible laser, optical modulation and optical limiting applications of xanthene dyes are discussed.

引用

页码：439 / 444

页数：6

共 21 条

[1] PHOTOPHYSICAL PROPERTIES OF LASER-DYES - PICOSECOND LASER FLASH-PHOTOLYSIS STUDIES OF RHODAMINE-6G, RHODAMINE-B AND RHODAMINE-101 [J].

BEAUMONT, PC ;

JOHNSON, DG ;

PARSONS, BJ .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (23) :4185-4191

[2]

BERLMAN IB, 1971, HDB FLUORESCENCE ARO

[3]

Boyd R. W., 2020, Nonlinear Optics

[4] STUDIES OF EFFECTS OF HYDROGEN BONDING ON ORIENTATIONAL RELAXATION USING PICOSECOND LIGHT PULSES [J].

CHUANG, TJ ;

EISENTHAL, KB .

CHEMICAL PHYSICS LETTERS, 1971, 11 (03) :368-+

[5] EXCITONIC STARK SHIFT - A COUPLING TO SEMIVIRTUAL BIEXCITONS [J].

COMBESCOT, M ;

COMBESCOT, R .

PHYSICAL REVIEW LETTERS, 1988, 61 (01) :117-120

[6]

HAMMOND PR, 1986, Patent No. 4622400

[7] RHODAMINE-B AND RHODAMINE-101 AS REFERENCE SUBSTANCES FOR FLUORESCENCE QUANTUM YIELD MEASUREMENTS [J].

KARSTENS, T ;

KOBS, K .

JOURNAL OF PHYSICAL CHEMISTRY, 1980, 84 (14) :1871-1872

[8] Effects of excited-state absorption and amplified spontaneous emission in a high-average-power dye laser amplifier pumped by copper vapor lasers [J].

Maruyama, Y ;

Kato, M ;

Arisawa, T .

OPTICAL ENGINEERING, 1996, 35 (04) :1084-1087

[9]

Nunzi J. M., 1996, Nonlinear Optics, Principles, Materials, Phenomena, and Devices, V15, P243

[10]

Nunzi J. M., 1991, Nonlinear Optics, Principles, Materials, Phenomena and Devices, V1, P19

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