Hydrogenation and Oxidation Reactions Involving Ruthenium Supported Catalysts

被引：11

作者：

Joshi, Rikesh ^{[1
]}

Chudasama, Uma ^{[1
]}

机构：

[1] Maharaja Sayajirao Univ Baroda, Fac Engn & Technol, Dept Appl Chem, Vadodara 390001, Gujarat, India

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2010年 / 49卷 / 06期

关键词：

RH3+-DIAMINE COMPLEXES; CARBONYLATION; PHOSPHATE; RH3+;

D O I：

10.1021/ie9008309

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The present Study involves synthesis and characterization of M(IV) phosphates and tungstates which are inorganic cation exchangers of the class of tetravalent metal acid (tma) salts possessing structural hydroxyl groups, the H of the structural -OH being the cation exchange sites, which indicates good potential for application as supports in heterogenized homogeneous catalysis. Ru(III) has been exchanged onto these materials by an ion exchange technique and catalytic activity investigated for oxidation of benzyl alcohol and styrene. Further, Ru(III) has been reduced to Ru(0) and catalytic activity has been explored for hydrogenation of 1-octene, nitro benzene, and cyclohexanone.

引用

页码：2543 / 2547

页数：5

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