C2-symmetric bicyclo[2.2.2]octadienes as chiral ligands:: Their high performance in rhodium-catalyzed asymmetric arylation of N-tosylarylimines

被引：361

作者：

Tokunaga, N ^{[1
]}

Otomaru, Y ^{[1
]}

Okamoto, K ^{[1
]}

Ueyama, K ^{[1
]}

Shintani, R ^{[1
]}

Hayashi, T ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 42期

关键词：

D O I：

10.1021/ja044790e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric synthesis of diarylmethylamines with high enantioselectivity (95-99% ee) was realized by use of a new C2-symmetric diene ligand, (1R,4R)-2,5-diphenylbicyclo[2.2.2]octa-2,5-diene (Ph-bod*), for the rhodium-catalyzed asymmetric arylation of N-tosylarylimines with arylboroxines. Copyright © 2004 American Chemical Society.

引用

页码：13584 / 13585

页数：2

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