Thermodynamics of the equilibrium of the reaction between (5,10,15,20-tetra(2-methoxyphenyl)porphinato)chloroindium(III) and pyridine

被引：1

作者：

Bichan, N. G. ^{[1
]}

Ovchenkova, E. N. ^{[1
]}

Mozhzhukhina, E. G. ^{[1
]}

Lomova, T. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Krestov Inst Solut Chem, Ivanovo 153045, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2017年 / 91卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

substituted indium(III) porphyrin; pyridine; porphyrin-pyridine supramolecules; thermodynamics of formation; chemical structure; spectral properties; prospects for practical application; SEMIEMPIRICAL METHODS; COMPLEXES; OPTIMIZATION; PARAMETERS; PORPHYRINS; DESIGN; STATES;

D O I：

10.1134/S0036024417070068

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The results from thermodynamic and quantum-chemical studies of the reversible reaction between (5,10,15,20-tetra(2-methoxyphenyl)porphinato)chloroindium(III) and pyridine are reported. The main physicochemical parameters of properties of its supramolecular products are obtained and analyzed. The addition of pyridine molecules to metalloporphyrin proceeds in one step to attain an equilibrium state with the formation of supramolecules with a stoichiometry of 2: 1; spectral characteristics and parameters of the stability of the latter are identified. The possibility of using substituted indium(III)porphyrin for further research in the field of hybrid solar cells is discussed.

引用

页码：1279 / 1284

页数：6

共 50 条

[21] Chemical Structure of Pyridine Complexes Of Oxo(5,10,15,20-Tetraphenyl-21H,23H-Porphinato) Niobium(V) Chloride According to Formation Thermodynamics/Kinetics And Spectroscopy Data
Motorina, E. V.
Mozhzhukhina, E. G.
Lomova, T. N.
JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 59 (08) : 1880 - 1890
[22] Kinetics of the chemical oxidation of (5,10,15,20-tetraphenyl-21H,23H-porphinato)(chloro)(aqua)iridium(III)
Tyulyaeva, E. Yu.
Bichan, N. G.
Mozhzhukhina, E. G.
Lomova, T. N.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2016, 90 (01) : 37 - 42
[23] A new polymeric framework formed by the self assembly of 5,10,15,20-tetra(3-pyridyl)porphyrin, HgI2 and C60
Taylor, SK
Jameson, GB
Boyd, PDW
SUPRAMOLECULAR CHEMISTRY, 2005, 17 (07) : 543 - 546
[24] Face-to-Face Stacking and Saddle Distortion of 5,10,15,20-Tetra(4-hydroxyphenyl)porphyrinatocopper(II) in Two New Solvates
Seidel, Ruediger W.
Goddard, Richard
Oppel, Iris M.
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2017, 47 (06) : 187 - 197
[25] Self-assembled monolayers formed by 5,10,15,20-tetra(4-pyridyl)porphyrin and cobalt 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine on iodine-passivated Au(111) as observed using electrochemical scanning tunneling microscopy and cyclic voltammetry
Thorgaard, Scott N.
Buehlmann, Philippe
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2012, 664 : 94 - 99
[26] Face-to-Face Stacking and Saddle Distortion of 5,10,15,20-Tetra(4-hydroxyphenyl)porphyrinatocopper(II) in Two New Solvates
Rüdiger W. Seidel
Richard Goddard
Iris M. Oppel
Journal of Chemical Crystallography, 2017, 47 : 187 - 197
[27] Synthesis of 5,10,15,20-tetra[3-(o- andm-carboranyl)butyl]porphyrins containing the C−B σ-bond
L. I. Zakharkin
V. A. Ol'shevskaya
R. P. Evstigneeva
V. N. Luzgina
L. E. Vinogradova
P. V. Petrovskii
Russian Chemical Bulletin, 1998, 47 : 340 - 342
[28] Thermodynamics and kinetics of the formation of the supramolecular complexes bisacetato(5,10,15,20-tetraphenylporphinate)zirconium(IV) with pyridine and imidazole
Tyulyaeva, E. Yu.
Lomova, T. N.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2010, 84 (05) : 749 - 754
[29] Synthesis of 5,10,15,20-tetra[3-(o- and m-carboranyl)butyl]porphyrins containing the C-B σ-bond
Zakharkin, LI
Ol'shevskaya, VA
Evstigneeva, RP
Luzgina, VN
Vinogradova, LE
Petrovskii, PV
RUSSIAN CHEMICAL BULLETIN, 1998, 47 (02) : 340 - 342
[30] Kinetics of the chemical oxidation of (5,10,15,20-tetraphenyl-21H,23H-porphinato)(chloro)(aqua)iridium(III)
E. Yu. Tyulyaeva
N. G. Bichan
E. G. Mozhzhukhina
T. N. Lomova
Russian Journal of Physical Chemistry A, 2016, 90 : 37 - 42

← 1 2 3 4 5 →