Thermodynamics of the equilibrium of the reaction between (5,10,15,20-tetra(2-methoxyphenyl)porphinato)chloroindium(III) and pyridine

被引：1
|
作者：
Bichan, N. G. [1 ]
Ovchenkova, E. N. [1 ]
Mozhzhukhina, E. G. [1 ]
Lomova, T. N. [1 ]
机构：
[1] Russian Acad Sci, Krestov Inst Solut Chem, Ivanovo 153045, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2017年 / 91卷 / 07期
基金：
俄罗斯基础研究基金会;
关键词：
substituted indium(III) porphyrin; pyridine; porphyrin-pyridine supramolecules; thermodynamics of formation; chemical structure; spectral properties; prospects for practical application; SEMIEMPIRICAL METHODS; COMPLEXES; OPTIMIZATION; PARAMETERS; PORPHYRINS; DESIGN; STATES;
D O I：
10.1134/S0036024417070068
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The results from thermodynamic and quantum-chemical studies of the reversible reaction between (5,10,15,20-tetra(2-methoxyphenyl)porphinato)chloroindium(III) and pyridine are reported. The main physicochemical parameters of properties of its supramolecular products are obtained and analyzed. The addition of pyridine molecules to metalloporphyrin proceeds in one step to attain an equilibrium state with the formation of supramolecules with a stoichiometry of 2: 1; spectral characteristics and parameters of the stability of the latter are identified. The possibility of using substituted indium(III)porphyrin for further research in the field of hybrid solar cells is discussed.
引用
收藏
页码：1279 / 1284
页数：6
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