Crystal structure and photo-induced property of two-dimensional silver(I) complex with 1,3,5-tris(benzylsulfanyl)benzene

被引：12
作者：
Suenaga, Y
Konaka, H
Sugimoto, T
Kuroda-Sowa, T
Maekawa, M
Munakata, M
机构：
[1] Kinki Univ, Dept Chem, Osaka 5778502, Japan
[2] Kinki Univ, Sci & Technol Res Inst, Osaka 5778502, Japan
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 04期
基金：
日本学术振兴会;
关键词：
silver(I) coordination polymer; 1,3,5-tris(benzylsulfanyl)benzene; two-dimensional sheet structure; photochromism;
D O I：
10.1016/S1387-7003(02)00780-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The silver(l) complex [Ag-2(3bsb)(2)(ClO4)(2)] (1) (3bsb; 1,3,5-tris(benzylsulfanyl)benzene) has been prepared and its molecular structure was determined by X-ray crystallography. In 1, the silver ion prefers a tetrahedral coordination geometry and produces a two-dimensional sheet structure containing dimeric units. Irradiation of this complex 1 with light changes its color from white to pink; heat or exposure to acetone vapor makes the irradiated sample revert back to white. However, only 3bsb has no characteristic like this photochromism. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：389 / 393
页数：5
相关论文
共 19 条
[1]   SUPRAMOLECULAR PHOTOCHEMISTRY [J].
BALZANI, V .
TETRAHEDRON, 1992, 48 (48) :10443-10514
[2]   HOMOLEPTIC COMPLEXES OF 2,2'-BIPYRIDINE [J].
CONSTABLE, EC .
ADVANCES IN INORGANIC CHEMISTRY, 1989, 34 :1-63
[3]   A NOVEL ORGANIC PHOTOCHROMIC [J].
COX, SD ;
DIRK, CW ;
MORAES, F ;
WELLMAN, DE ;
WUDL, F ;
SOLTIS, M ;
STROUSE, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (23) :7131-7133
[4]   PRESSURE TUNING SPECTROSCOPY AS A DIAGNOSTIC FOR PRESSURE-INDUCED REARRANGEMENTS (PIEZOCHROMISM) OF SOLID-STATE CU(II) COMPLEXES [J].
DRICKAMER, HG ;
BRAY, KL .
ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (02) :55-61
[5]   CONCERNING THERMOCHROMIC MECHANISM OF COPPER(II) AND NICKEL(II) COMPLEXES OF N,N-DIETHYLETHYLENEDIAMINE [J].
FERRARO, JR ;
BASILE, LJ ;
GARCIAINEGUEZ, LR ;
PAOLETTI, P ;
FABBRIZZI, L .
INORGANIC CHEMISTRY, 1976, 15 (10) :2342-2345
[6]   THERMOCHROMISM IN COPPER(II) COMPLEXES - STRUCTURES OF THE RED AND BLUE-VIOLET FORMS OF BIS(N,N-DIETHYLETHYLENEDIAMINE)COPPER(II) PERCHLORATE AND THE NONTHERMOCHROMIC VIOLET BIS(N-ETHYLETHYLENEDIAMINE)COPPER(II) PERCHLORATE [J].
GRENTHE, I ;
PAOLETTI, P ;
SANDSTROM, M ;
GLIKBERG, S .
INORGANIC CHEMISTRY, 1979, 18 (10) :2687-2692
[7]   NEW APPROACH FOR THE DESIGN OF INCLUSION COMPOUNDS [J].
HARDY, ADU ;
MACNICOL, DD ;
WILSON, DR .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1979, (07) :1011-1019
[8]   CHARGE-TRANSFER SPECTRA OF BIS(DIAMINE)COPPER(II) COMPLEXES AND THEIR CORRELATION WITH OTHER ELECTRONIC, VIBRATIONAL, AND THERMODYNAMIC PROPERTIES [J].
KENNEDY, BP ;
LEVER, ABP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (21) :6907-6913
[9]   SUPRAMOLECULAR CHEMISTRY - SCOPE AND PERSPECTIVES MOLECULES, SUPERMOLECULES, AND MOLECULAR DEVICES [J].
LEHN, JM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1988, 27 (01) :89-112
[10]  
LEVER ABP, 1971, INORG CHEM, V10, P2434
12