A mononuclear complex of norfloxacin with silver(I) and its properties

被引：53
作者：
Li, YX
Chen, ZF
Xiong, RG [1 ]
Xue, ZL
Ju, HX
You, XZ
机构：
[1] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 07期
基金：
中国国家自然科学基金;
关键词：
norfloxacin; silver; Ag+ Release; fluorescence; crystal structure;
D O I：
10.1016/S1387-7003(03)00115-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of norfloxacin (H-Norf) with AgNO3 yields an unusual mononuclear complex [Ag(H-Norf)(2)]NO3 (1) in which the local coordination environment around Ag+ ion is approximately linear with a N-Ag-N angle of 162.1(2)degrees. Larger concentration of Ag+ ions was found in water solution of 1. The unique bonding in I may lead to the readily release of Ag+ ion from 1, and leads to better antibacterial action in topical burn treatments. Strong blue fluorescent emission of 1 was also observed. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：819 / 822
页数：4
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