Hydrogen bonding in 1-carbamoylguanidinium methylphosphonate monohydrate

被引:5
作者
Brauer, DJ [1 ]
Kottsieper, KW [1 ]
机构
[1] Berg Univ Wuppertal, Fachbereich 9, D-42097 Wuppertal, Germany
关键词
All Open Access; Green;
D O I
10.1107/S0108270103005857
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, C2H7N4O+.CH4O3P-.H2O, crystallized with one carbamoylguanidinium cation, one methylphosphonate anion and one water molecule in the asymmetric unit. All H atoms of the carbamoylguanidinium ion are involved in a hydrogen-bonded network. The CH3PO2( OH) anions, together with the water molecules, build O-H...O hydrogen-bonded ribbons around a 21 screw axis parallel to the b axis. Neighbouring ribbons are not directly connected via hydrogen bonding. The carbamoylguanidinium cations are linked to these ribbons by N-H...O bridges and build a slightly buckled layer structure, the interlayer distance being b/2.
引用
收藏
页码:O244 / O246
页数:3
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