Ultrasonic effects on PP/PS/clay nanocomposites during continuous melt compounding process

被引:15
作者
Kim, Kyung Yl
Ju, Dong Uk
Nam, Gi Joon
Lee, Jae Wook
机构
[1] Sogang Univ, Dept Chem & Biomol Engn, Seoul 121742, South Korea
[2] LS Cable Ltd, R&D Ctr, Kyonggi Do 431080, South Korea
关键词
extrusion; nanocomposite; polypropylene; polystyrene; ultrasonic wave;
D O I
10.1002/masy.200750346
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polymer blend/clay nanocomposites were prepared by ultrasonic-assisted continuous extrusion process. This process was employed to enhance the compatibility between two polymers, and nano-scale dispersion between the polymer blend and organically modified clay. Materials were linear polypropylene and polystyrene with 3 phr loading of organophilic montmorillonite clay. The effectiveness of the proposed ultrasonic-assisted process on the polypropylene/polystyrene/clay nanocomposites was confirmed by rheological property measurements and structural analysis by scanning electron microscope and X-ray diffraction. The sonication during extrusion was effective in improving the compatibility between polypropylene and polystyrene. Also, it led to enhanced breakup of the clay agglomerates. The observed clay was in the exfoliated state from the X-ray diffraction analysis.
引用
收藏
页码:283 / 288
页数:6
相关论文
共 12 条
[1]  
[Anonymous], 1992, Current Trends in Sonochemistry
[2]  
Kim H, 2002, KOREA-AUST RHEOL J, V14, P121
[3]   Effect of ultrasonic wave on the degradation of polypropylene melt and morphology of its blend with polystyrene [J].
Kim, H ;
Lee, JW .
POLYMER, 2002, 43 (08) :2585-2589
[4]   Rheological properties of polypropylene modified by high-intensity ultrasonic waves [J].
Kim, KY ;
Nam, GJ ;
Lee, SM ;
Lee, JW .
JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 99 (05) :2132-2137
[5]  
KIM KY, 2006, SPE ANTEC TECH PAPER, P1824
[6]   NOVEL PREFERRED ORIENTATION IN INJECTION-MOLDED NYLON 6-CLAY HYBRID [J].
KOJIMA, Y ;
USUKI, A ;
KAWASUMI, M ;
OKADA, A ;
KURAUCHI, T ;
KAMIGAITO, O ;
KAJI, K .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1995, 33 (07) :1039-1045
[7]   A house of cards structure in polypropylene/clay nanocomposites under elongational flow [J].
Okamoto, M ;
Nam, PH ;
Maiti, P ;
Kotaka, T ;
Hasegawa, N ;
Usuki, A .
NANO LETTERS, 2001, 1 (06) :295-298
[8]   Characteristics of polystyrene/polyethylene/clay nanocomposites prepared by ultrasound-assisted mixing process [J].
Ryu, JG ;
Kim, H ;
Lee, JW .
POLYMER ENGINEERING AND SCIENCE, 2004, 44 (07) :1198-1204
[9]   Development of poly(methyl methacrylate)-clay nanocomposites by using power ultrasonic wave [J].
Ryu, JG ;
Lee, JW ;
Kim, H .
MACROMOLECULAR RESEARCH, 2002, 10 (04) :187-193
[10]  
Schnabel W., 1981, POLYM DEGRADATION