Characterizing the emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans from crematories and their impacts to the surrounding environment

被引:103
作者
Wang, LC
Lee, WJ
Lee, WS
Chang-Chien, GP
Tsai, PJ
机构
[1] Natl Cheng Kung Univ, Coll Med, Grad Inst Environm & Occupat Hlth, Tainan 70428, Taiwan
[2] Natl Cheng Kung Univ, Dept Environm Engn, Tainan 70101, Taiwan
[3] Cheng Shiu Inst Technol, Dept Chem Engn, Kaohsiung 833, Taiwan
关键词
D O I
10.1021/es0208714
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study was set out to characterize PCDD/F emissions from crematories and assess their impacts on the surrounding environment. Two crematories located in southern Taiwan were investigated, including the one (Cl) with no air pollution control device installed and the other (C2) installed with a bag filter. Results show the mean PCDD/F emissions (11% oxygen) from the stacks of C1 and C2 were 2.36 and 0.322 ng I-TEQ Nm(-3), respectively. The mean emission factors for C1 and C2 were 13.6 and 6.11 mug I-TEQ body(-1), respectively. The removal efficiency of the bag filter on PCDD/Fs was 55.1%. The estimated PCDD/F emission rate for all crematories in Taiwan was 0.838 g I-TEQ yr(-1) accounting for 227% and 112% of the annual emissions from all medical waste incinerators and municipal waste incinerators, respectively. The above results indicate that PCDD/F emissions from crematories were quite significant. To assess the impact of PCDD/F emissions from a crematory to the surrounding environment, ambient air samples were collected from the downwind site of C1 with the maximum ground concentration. We found the estimated maximum ground concentration at the downwind site of C1 (= 0.521 pg I-TEQ Nm(-3)) was much higher than that found at the background, rural area, residential area, urban area, and industrial area (= 0.006, 0.023, 0.052, 0.093, and 0.190 pg I-TEQ Nm(-3), respectively). The above results suggest that PCDD/F emissions from a crematory did significantly affect its surrounding environment. In conclusion, a proper control strategy should be taken immediately in order to eliminate PCDD/F emissions from crematories.
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页码:62 / 67
页数:6
相关论文
共 17 条
[1]   PCDD/PCDF from emission sources and ambient air in northeast Spain [J].
Abad, E ;
Caixach, J ;
Rivera, J .
CHEMOSPHERE, 1997, 35 (03) :453-463
[2]   Observations on PAH, PCB, and PCDD/F trends in UK urban air, 1991-1995 [J].
Coleman, PJ ;
Lee, RGM ;
Alcock, RE ;
Jones, KC .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1997, 31 (07) :2120-2124
[3]   An updated inventory of potential PCDD and PCDF emission sources in the UK [J].
Eduljee, GH ;
Dyke, P .
SCIENCE OF THE TOTAL ENVIRONMENT, 1996, 177 :303-321
[4]  
FLEDLER H, 1993, ORGANOHALOGEN COMPD, V11, P221
[5]  
FLEDLER H, 1996, CHEMOSPHERE, V32, P55
[6]   PCDD/F mass balance in the flue gas cleaning units of a MSW incineration plant [J].
Giugliano, M ;
Cernuschi, S ;
Grosso, M ;
Miglio, R ;
Aloigi, E .
CHEMOSPHERE, 2002, 46 (9-10) :1321-1328
[7]   Seasonal, anthropogenic. air mass, and meteorological influences on the atmospheric concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs):: Evidence for the importance of diffuse combustion sources [J].
Lee, RGM ;
Green, NJL ;
Lohmann, R ;
Jones, KC .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1999, 33 (17) :2864-2871
[8]   Testing the USA EPA's ISCST-Version 3 model on dioxins: a comparison of predicted and observed air and soil concentrations [J].
Lorber, M ;
Eschenroeder, A ;
Robinson, R .
ATMOSPHERIC ENVIRONMENT, 2000, 34 (23) :3995-4010
[9]   Total TEQ emissions (PCDD/F and PCB) from industrial sources [J].
Luthardt, P ;
Mayer, J ;
Fuchs, J .
CHEMOSPHERE, 2002, 46 (9-10) :1303-1308
[10]  
OLIE K, 1977, Chemosphere, V6, P455, DOI 10.1016/0045-6535(77)90035-2