Access to enantiopure polycyclic β-lactams by Diels-Alder reaction of novel inner-outer-ring 2-(silyloxy)dienes with a carbacepham skeleton

被引：10

作者：

Alcaide, B ^{[1
]}

de Murga, RM ^{[1
]}

Pardo, C ^{[1
]}

Rodríguez-Ranera, C ^{[1
]}

机构：

[1] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Organ 1, E-28040 Madrid, Spain

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 39期

关键词：

beta-lactam; 2-azetidinone; carbacepham; diene; Diels-Alder cycloaddition;

D O I：

10.1016/j.tetlet.2004.08.022

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of unprecedented inner-outer-ring 2-[tert-butyidimethylsilyloxy]dienes with a carbacepham structure in optically pure form and their totally pi-facial endo selective Diels-Alder reactions to structurally novel polycyclic beta-lactams is reported. (C) 2004 Published by Elsevier Ltd.

引用

页码：7255 / 7259

页数：5

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