The capillary and porous structure of the protein-cellulose complexes of Arctic brown algae Laminaria digitata and Saccharina latissima

被引:7
作者
Bogolitsyn, Konstantin G. [1 ,2 ]
Parshina, Anastasia E. [1 ]
Ivanchenko, Nikolai L. [1 ]
Bogdanovich, Nikolai I. [1 ]
Arkhilin, Mikhail A. [1 ]
机构
[1] Northern Arct Fed Univ, 17 Northern Dvina Emb, Arkhangelsk 163002, Russia
[2] N Laverov Fed Ctr Integrated Arct Res, Inst Ecol Problems North, 23 Northern Dvina Emb, Arkhangelsk 163000, Russia
关键词
Brown algae; Cellulose; Dyes; Hammett method; Porosity; Sorption; BLUE;
D O I
10.1007/s10570-022-04707-2
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Due to their specific physicochemical, capillary, and porous properties, the cellulosic sorbents from macrophytes have a high number of possible uses. The number of studies of alternative sources of cellulose is nowadays increasing. One of the most interesting cellulose-containing components of brown algae biomass is protein-cellulose complexes (PCC). The capillary and porous structure of protein-cellulose complexes of brown algae Laminaria digitata and Saccharina latissima was studied. The mesoporous structure of PCC was revealed using the nitrogen adsorption method. The surface area of protein-cellulose complexes is 5.31 m(2)/g and 2.94 m(2)/g for PCC S. latissima and PCC L. digitata, respectively. The adsorption of cationic methylene blue was more effective (maximum uptake capacity 24 mg/g) than anionic methyl orange (maximum uptake capacity 11 mg/g), which could be explained by the surface properties of protein-cellulose complexes and their charge, as well as the acid-base features of the dyes. The obtained results highlight the potential of the studied materials for the adsorption of organic toxicants.
引用
收藏
页码:7037 / 7048
页数:12
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