Piperidine-CO2-H2O molecular complex

被引:14
作者
Jiang, HM [1 ]
Novak, I [1 ]
机构
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
关键词
piperidine; molecular complex; crystal structure;
D O I
10.1016/S0022-2860(02)00545-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Piperidine forms a molecular complex with CO2 and H2O through hydrogen bonding. The formation of the complex was found to be a reversible process. The complex decomposes to the original components at room temperature. The structure of the complex obtained via X-ray diffraction is described and compared to the previously reported 4-methylpiperidine carboxylate. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:177 / 183
页数:7
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