Reversible luminescent reaction of amines with copper(I) cyanide

被引：59
作者：
Ley, Amanda N. [1 ]
Dunaway, Lars E. [1 ]
Brewster, Timothy P. [1 ]
Dembo, Matthew D. [1 ]
Harris, T. David [2 ]
Baril-Robert, Francois [3 ]
Li, Xiaobo [3 ]
Patterson, Howard H. [3 ]
Pike, Robert D. [1 ]
机构：
[1] Coll William & Mary, Dept Chem, Williamsburg, VA 23187 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[3] Univ Maine, Dept Chem, Orono, ME 04469 USA
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 25期
基金：
美国国家科学基金会;
关键词：
VAPOCHROMIC BEHAVIOR; STRUCTURAL BASIS; NETWORKS; SENSORS; ADDUCTS; LIGANDS; BASES;
D O I：
10.1039/c002351e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Copper(I) cyanide exposed to various liquid or vapor-phase amines (L) at ambient temperature produces a variety of visible photoluminescence colors via reversible formation of amine adducts. The adducts show phase matches to authentic (CuCN)L(n), n = 0.75-2.0, produced by heating CuCN with liquid amine.
引用
收藏
页码：4565 / 4567
页数：3
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