Photoconversion of a redox-active self-assembled monolayer: In situ probing of photoinduced CO dissociation from a triruthenium cluster center on gold

被引：31

作者：

Abe, M ^{[1
]}

Masuda, T ^{[1
]}

Kondo, T ^{[1
]}

Uosaki, K ^{[1
]}

Sasaki, Y ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Kita Ku, Sapporo, Hokkaido 0600810, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 03期

关键词：

electrochemistry; monolayers; photochemistry; surface chemistry;

D O I：

10.1002/anie.200460651

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photoresponsive self-assembled monolayers (SAMs): Photoexcitation of a CO-bearing trinuclear ruthenium cluster assembled on an Au(111) electrode results in dissociation of CO to form a H2O-terminated SAM (see picture). This is the first well-defined example of clean conversion of a redox-active molecular film by using light stimulus. (Figure Presented).

引用

页码：416 / 419

页数：4

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