TBT and its metabolites in sediments: Survey at a German coastal site and the central Baltic Sea

被引：35

作者：

Abraham, Marion ^{[1
]}

Westphal, Lina ^{[1
]}

Hand, Ines ^{[1
]}

Lerz, Astrid ^{[1
]}

Jeschek, Jenny ^{[1
]}

Bunke, Dennis ^{[1
]}

Leipe, Thomas ^{[1
]}

Schulz-Bull, Detlef ^{[1
]}

机构：

[1] Leibniz Inst Balt Sea Res Warnemunde, Dept Marine Chem, Seestr 15, D-18119 Rostock, Germany

来源：

MARINE POLLUTION BULLETIN | 2017年 / 121卷 / 1-2期

关键词：

Organotin; monobutyltin; dibutyltin; tributyltin; Baltic Sea; ORGANOTIN COMPOUNDS; SURFACE SEDIMENTS; MARINE-SEDIMENTS; TRIBUTYLTIN TBT; WATER SAMPLES; DEGRADATION; ENVIRONMENT; CONTAMINATION; ACCUMULATION; PERSISTENCE;

D O I：

10.1016/j.marpolbul.2017.06.020

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Since the 1950s the organotin compound tributyltin (TBT) was intensively used in antifouling paints for marine vessels and it became of concern for the marine environment. Herein, we report on a study from 2015 on TBT and its metabolites monobutyltin (MBT) and dibutyltin (DBT) in sediments from the central Baltic Sea and a Baltic Sea coastal site with strong harbor activities (Warnemiinde). Sublayers from a sediment core from the Arkona Basin were analyzed to investigate the long term organotin pressure for the Baltic Sea. For the central Baltic Sea total organotin (MBT+DBT+TBT) ranged from 100 to 500 ng/g TOC with distinct areas of high organotin content probably due to historical inputs. For the coastal site total organotin ranged from 10,000 to 60,000 ng/g TOC. MBT and DBT were the predominant organotin species detected. Overall, the data obtained indicate the progress of TBT degradation at the investigated sites.

引用

页码：404 / 410

页数：7

共 34 条

[1] Tributyltin: case study of a chronic contaminant in the coastal environment [J].

Alzieu, C .

OCEAN & COASTAL MANAGEMENT, 1998, 40 (01) :23-36

[2] TIN CONTAMINATION IN ARCACHON BAY - EFFECTS ON OYSTER SHELL ANOMALIES [J].

ALZIEU, C ;

SANJUAN, J ;

DELTREIL, JP ;

BOREL, M .

MARINE POLLUTION BULLETIN, 1986, 17 (11) :494-498

[3]

[Anonymous], 2008, STATE EVOLUTION BALT, DOI [10.1002/9780470283134.ch14, DOI 10.1002/9780470283134.CH14]

[4] Environmental levels, toxicity and human exposure to tributyltin (TBT)-contaminated marine environment. A review [J].

Antizar-Ladislao, Blanca .

ENVIRONMENT INTERNATIONAL, 2008, 34 (02) :292-308

[5] Concentrations of the antifouling compound Irgarol 1051 and of organotins in water and sediments of German North and Baltic Sea marinas [J].

Biselli, S ;

Bester, K ;

Hühnerfuss, H ;

Fent, K .

MARINE POLLUTION BULLETIN, 2000, 40 (03) :233-243

[6]

Brfigmann L. L., 1990, LIMNOLOGICA, V20, P15

[7] Spatial and temporal distribution of tributyltin (TBT) in seawater, sediments and bivalves from coastal areas of Korea during 2001-2005 [J].

Choi, Minkyu ;

Choi, Hee-Gu ;

Moon, Hyo-Bang ;

Kim, Gui-Young .

ENVIRONMENTAL MONITORING AND ASSESSMENT, 2009, 151 (1-4) :301-310

[8] SOURCES AND RATE OF DEGRADATION OF TRI(N-BUTYL)TIN IN MARINE-SEDIMENTS NEAR AUCKLAND, NEW-ZEALAND [J].

DEMORA, SJ ;

STEWART, C ;

PHILLIPS, D .

MARINE POLLUTION BULLETIN, 1995, 30 (01) :50-57

[9] Organotin contamination in sediments from the Western Mediterranean enclosures following 10 years of TBT regulation [J].

Díez, S ;

Abalos, M ;

Bayona, JM .

WATER RESEARCH, 2002, 36 (04) :905-918

[10] Persistence and degradation pathways of tributyltin in freshwater and estuarine sediments [J].

Dowson, PH ;

Bubb, JM ;

Lester, JN .

ESTUARINE COASTAL AND SHELF SCIENCE, 1996, 42 (05) :551-562

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