Corrosion Inhibition of Q235 Steel by a Novel Imidazoline Compound under H2S and CO2 Coexistence

被引:22
|
作者
Hu Song-Qing [1 ]
Hu Jian-Chun [1 ]
Fan Cheng-Cheng [1 ]
Mi Si-Qi [1 ]
Zhang Jun [1 ]
Guo Wen-Yue [1 ]
机构
[1] China Univ Petr, Coll Phys Sci & Technol, Dongying 257061, Shandong, Peoples R China
关键词
Corrosion inhibitor; Weight loss method; Electrochemical method; Quantum chemistry; MOLECULAR-STRUCTURE; MILD-STEEL; DERIVATIVES; QSAR;
D O I
10.3866/PKU.WHXB20100809
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We synthesized a new imidazoline compound, 1-(2-amido-thioureaethyl)-2-pentadecyl. imidazoline (IM-S). The corrosion inhibition performance and adsorption behavior for mild steel corrosion under H2S and CO2 coexistence were investigated by weight loss method, polarization curve, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM). The results indicated that IM-S had excellent corrosion inhibition performance, and both cathodic and anodic processes of mild steel corrosion were suppressed. The highest inhibition efficiency was 92.74%. We found that the adsorption of IM-S on mild steel could be fitted to a Langmuir isotherm equation, and it belonged to a mix. type adsorption, which was mainly dominated by chemisorption. The relationship between the molecular structure of IM-S and the inhibition efficiency was investigated using quantum chemical calculations.
引用
收藏
页码:2163 / 2170
页数:8
相关论文
共 21 条
  • [1] Quantum chemical studies on some imidazole derivatives as corrosion inhibitors for iron in acidic medium
    Bereket, G
    Hür, E
    Ögretir, C
    [J]. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2002, 578 : 79 - 88
  • [2] Thermodynamic properties of 2,5-bis(4-methoxyphenyl)-1,3,4-oxadiazole as a corrosion inhibitor for mild steel in normal sulfuric acid medium
    Bouklah, M.
    Hammouti, B.
    Lagrenee, M.
    Bentiss, F.
    [J]. CORROSION SCIENCE, 2006, 48 (09) : 2831 - 2842
  • [3] Cao CN., 2004, PRINCIPLE CORROSION
  • [4] Reactivity properties of derivatives of 2-imidazoline:: An ab initio DFT study
    Cruz, J
    Martínez-Aguilera, LMR
    Salcedo, R
    Castro, M
    [J]. INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2001, 85 (4-5) : 546 - 556
  • [5] BINDING-ENERGIES IN ATOMIC NEGATIVE-IONS .2.
    HOTOP, H
    LINEBERGER, WC
    [J]. JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1985, 14 (03) : 731 - 750
  • [6] HU JC, 2009, QINGDAO U ENG TECHNO, V24, P90
  • [7] QSAR and Molecular Design of Imidazoline Derivatives as Corrosion Inhibitors
    Hu Song-Qing
    Hu Jian-Chun
    Shi Xin
    Zhang Jun
    Guo Wen-Yue
    [J]. ACTA PHYSICO-CHIMICA SINICA, 2009, 25 (12) : 2524 - 2530
  • [8] Berberine as a natural source inhibitor for mild steel in 1 M H2SO4
    Li, Y
    Zhao, P
    Liang, Q
    Hou, BR
    [J]. APPLIED SURFACE SCIENCE, 2005, 252 (05) : 1245 - 1253
  • [9] Liu F.G., 2008, STUDY CORROSION MECH
  • [10] LIU X, 2009, CHIN SOC CORROS PROT, V29, P333