Hydration products of C3A, C3S and Portland cement in the presence of CaCO3

被引：411

作者：

Kakali, G ^{[1
]}

Tsivilis, S ^{[1
]}

Aggeli, E ^{[1
]}

Bati, M ^{[1
]}

机构：

[1] Natl Tech Univ Athens, Dept Chem Engn, Inorgan & Analyt Chem Lab, GR-15773 Athens, Greece

来源：

CEMENT AND CONCRETE RESEARCH | 2000年 / 30卷 / 07期

关键词：

hydration products; Ca3Al2O6; Ca3SiO5; CaCO3; limestone cement;

D O I：

10.1016/S0008-8846(00)00292-1

中图分类号：

TU [建筑科学];

学科分类号：

0813 ;

摘要：

The subject of this work is the effect of calcium carbonate on the hydration products of C(3)A, C3S and cement. Pastes made from C(3)A and C3S containing 0%, 10%, 20% and 35% w/w of chemical grade CaCO3, as well as pastes made from Portland cement containing 0%, 10%, 20% and 35% w/w limestone, were examined after 1, 2, 7 and 28 days of hydration. The hydration products in C3S and C(3)A pastes containing CaCO3, as well as in limestone cement pastes, were identified by means of powder diffraction. The effect of calcium carbonate on the hydration procedure was also recorded. It is concluded that in pastes containing CaCO3, either as a chemical reagent or as a limestone constituent, the ettringite's transformation to monosulfate is delayed, while calcium aluminate monocarbonate is preferably formed instead of monosulfate even at early ages. In addition, the hydration of C3S is accelerated and formation of some carbosilicate is observed. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1073 / 1077

页数：5

共 27 条

[1]

ADAMS LD, 1990, AM SOC TEST MATER, V1064, P41, DOI 10.1520/STP23470S

[2]

BARKER AP, 1991, BLENDED CEMENTS IN CONSTRUCTION, P107

[3]

Baron J., 1987, WORLD CEMENT, V18, P100

[4]

DHIR R, 1994, IMPACT ENV 197 1 CON

[5]

*EUR COMM STAND, 1996, 1971 PREN EUR COMM S

[6] Effect of limestone filler on the sulfate resistance of low C3A Portland cement [J].

González, MA ;

Irassar, EF .

CEMENT AND CONCRETE RESEARCH, 1998, 28 (11) :1655-1667

[7]

GOSHET G, 1993, LIMESTONE FILLED CEM

[8]

INGRAM K, 1990, AM SOC TEST MATER, V1064, P14, DOI 10.1520/STP23467S

[9]

Ingram KD, 1992, P 9 INT C CHEM CEM N, VIII, P180

[10]

KLEMM WA, 1990, AM SOC TEST MATER, V1064, P60, DOI 10.1520/STP23472S

← 1 2 3 →