KINETICS AND MECHANISM OF CARBAMATE REACTION OF 4-HYDROXYBENZYL ALCOHOL WITH PHENYL ISOCYANATE

被引：12

作者：

Yang, Pengfei ^{[1
,2
]}

Li, Tianduo ^{[1
,2
]}

Li, Junying ^{[3
]}

Zhu, Xuwei ^{[2
]}

Xia, Yongmei ^{[2
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Peoples R China

[2] Shandong Inst Light Ind, Instrumental Anal Ctr, Jinan 250353, Peoples R China

[3] Shandong Inst Light Ind, Sch Chem Engn, Jinan 250353, Peoples R China

来源：

PROGRESS IN REACTION KINETICS AND MECHANISM | 2010年 / 35卷 / 01期

基金：

中国国家自然科学基金;

关键词：

isocyanate; in-situ IR; polyurethane; carbamate reaction; 4-hydroxybenzyl alcohol; induction; DIISOCYANATE;

D O I：

10.3184/146867809X12583840521471

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of 4-hydroxybenzyl alcohol with phenyl isocyanate in 1,4-dioxane was investigated, using in-situ FT-IR as the main tool. It was found that there was a remarkable induction phase in the reaction. Further, the reaction between isocyanate and the two types of hydroxyl groups in 4-hydroxybenzyl alcohol falls into two phases, with the phenolic hydroxyl being unexpectedly more reactive than the alcoholic hydroxyl. The reaction kinetics were also studied, and the activation energies were calculated to be 46.4 kJ mol(-1), 35.2 kJ mol(-1) and 41.5 kJ mol(-1) for the induction, phenolic and alcoholic phases, respectively.

引用

页码：93 / 104

页数：12

共 50 条

[41] Anti-oxidative effects of 4-hydroxybenzyl alcohol in astrocytes confer protective effects in autocrine and paracrine manners
Luo, Lidan
Kim, Seung-Woo
Lee, Hye-Kyung
Kim, Il-Doo
Lee, Hahnbie
Lee, Ja-Kyeong
PLOS ONE, 2017, 12 (05):
[42] QUINONE METHIDE FROM 4-HYDROXYBENZYL ALCOHOL DIACETATE - (PARA-ACETOXY)BENZYLATION OF BETA-DICARBONYLS
SANNER, MA
STANSBERRY, M
WEIGELT, C
MICHNE, WF
TETRAHEDRON LETTERS, 1992, 33 (37) : 5287 - 5290
[43] Novel Adenosine Analog, N6-(4-Hydroxybenzyl)-Adenosine, Dampens Alcohol Drinking and Seeking Behaviors
Hong, Sa-Ik
Peyton, Lee
Chern, Yijuang
Choi, Doo-Sup
JOURNAL OF PHARMACOLOGY AND EXPERIMENTAL THERAPEUTICS, 2019, 371 (02): : 260 - 267
[44] Kinetics and mechanism for the reaction of phenyl radical with formaldehyde
Choi, YM
Xia, WS
Park, J
Lin, MC
JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (30): : 7030 - 7035
[45] Microreactor assisted method for studying isocyanate-alcohol reaction kinetics
Lopez, Christian Orlando Camacho
Fejes, Zsolt
Viskolcz, Bela
JOURNAL OF FLOW CHEMISTRY, 2019, 9 (03) : 199 - 204
[46] Voltammetric Studies of 1,4-dihydroxybenzene and 4-hydroxybenzyl Alcohol Prepared in Aqueous Solutions at Various pH Values
Barham, Ahmad S.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2015, 162 (06) : G36 - G40
[47] Catalytic Kinetics and Mechanism Transformation of Fe(acac)3 on the Urethane Reaction of 1,2-Propanediol with Phenyl Isocyanate
Yang, Pengfei
Li, Tianduo
Li, Junying
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2013, 45 (10) : 623 - 628
[48] THERMAL AND PHOTO-OXIDATION OF POLYOLEFINS IN THE PRESENCE OF 3,5-DITERTIARYBUTYL 4-HYDROXYBENZYL THIOGLYCOLLATE, ZINC DIETHYLDITHIO CARBAMATE, AND IRGANOX 1076
KOLAWOLE, EG
JOURNAL OF APPLIED POLYMER SCIENCE, 1982, 27 (09) : 3437 - 3448
[49] Neuroprotective effect of 4-hydroxybenzyl alcohol against transient focal cerebral ischemia via anti-apoptosis in rats
Yu, Shan-Shan
Zhao, Jing
Zhen, Wei-Ping
Zhao, Yong
BRAIN RESEARCH, 2010, 1308 : 167 - 175
[50] The antidepressant effect of 4-hydroxybenzyl alcohol 2-naphthoate through monoaminergic, GABAergic system and BDNF signaling pathway
Zhang, Di
Zhu, Hong-yan
Bian, Xing-bo
Zhao, Yan
Zang, Pu
Gao, Yu-gang
Zhang, Lian-xue
NATURAL PRODUCT RESEARCH, 2020, 34 (16) : 2328 - 2331

← 1 2 3 4 5 →