Octahedral cluster Mo complexes (Bz3NH)3[Mo6OCl13] and (Bz3NH)2[Mo6Cl14] • 2CH3CN:: Synthesis, crystal structure and properties

被引：6

作者：

Kozhomuratova, Zh. S. ^{[1
]}

Naumov, N. G. ^{[1
]}

Naumov, D. Yu. ^{[1
]}

Uskov, E. M. ^{[1
]}

Fedorov, V. E. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 33卷 / 03期

关键词：

D O I：

10.1134/S1070328407030104

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The salts (Bz(3)NH)(3)[Mo6OCl13] (1) and (Bz(3)NH)(2)[Mo6Cll(4)]center dot 2CH3CN (II) were obtained by reacting melted tribenzylamine with cluster Mo compounds. Compound II contains a known cluster anionic complex [Mo6Cl14](2-). Compound I includes novel cluster anionic complex [Mo6OCl13](3-), where one internal Cl atom is replaced by the O atom. Complex II exhibits phosphorescence in a long-wavelength region of visible spectrum.

引用

页码：213 / 221

页数：9

共 37 条

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