Anatase-rutile transformation through high-temperature annealing of titania films produced by ultrasonic spray pyrolysis

被引：99
作者：
Nakaruk, A. [1 ]
Ragazzon, D. [1 ]
Sorrell, C. C. [1 ]
机构：
[1] Univ New S Wales, Sch Mat Sci & Engn, Sydney, NSW 2052, Australia
来源：
THIN SOLID FILMS | 2010年 / 518卷 / 14期
关键词：
Titanium dioxide; Ultrasonic spray pyrolysis; Glancing angle X-ray diffraction; Optical properties; TIO2; THIN-FILMS; DEPOSITION SPD TECHNIQUE; OPTICAL-PROPERTIES; PHOTOCATALYTIC PROPERTIES; OXIDE FILM; PHASE; FABRICATION; HYDROGEN; WATER; PHOTOLUMINESCENCE;
D O I：
10.1016/j.tsf.2009.10.109
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Titanium dioxide films were prepared by ultrasonic spray pyrolysis on (0001) alpha-quartz substrates at 400 degrees C and/or annealed in air at 600 degrees, 800 degrees, or 1000 degrees C. The as-deposited films at 400 degrees C (50 nm grains) and annealed at 600 degrees C (100 nm grains) showed single-phase anatase of high transparency in the visible region. Films annealed at 800 degrees C and 1000 degrees C showed mixed-phase anatase (100 nm grains) plus rutile (700 nm agglomerates) and pure rutile, (700 nm grains), respectively. Raman and X-ray data indicate the presence of residual stress in the films, which may arise from contamination, silicon diffusion into the films, and/or oxygen deficiency. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：3735 / 3742
页数：8
相关论文
共 76 条
  • [1] Preparation and characterisation of TiO2 thick films by gel oxidation
    Abdullah, H. Z.
    Sorrell, C. C.
    [J]. PRICM 6: SIXTH PACIFIC RIM INTERNATIONAL CONFERENCE ON ADVANCED MATERIALS AND PROCESSING, PTS 1-3, 2007, 561-565 : 2167 - 2170
  • [2] Preparation and characterisation of TiO2 thick films fabricated by anodic oxidation
    Abdullah, H. Z.
    Sorrell, C. C.
    [J]. PRICM 6: SIXTH PACIFIC RIM INTERNATIONAL CONFERENCE ON ADVANCED MATERIALS AND PROCESSING, PTS 1-3, 2007, 561-565 : 2159 - 2162
  • [3] Preparation and characterisation of TiO2 thick films fabricated by electrophoretic deposition
    Abdullah, H. Z.
    Sorrell, C. C.
    [J]. PRICM 6: SIXTH PACIFIC RIM INTERNATIONAL CONFERENCE ON ADVANCED MATERIALS AND PROCESSING, PTS 1-3, 2007, 561-565 : 2163 - 2166
  • [4] [Anonymous], 1989, HDB PROPERTIES TECHN
  • [5] Effect of rutile phase on the photocatalytic properties of nanocrystalline titania during the degradation of p-coumaric acid
    Bacsa, RR
    Kiwi, J
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 1998, 16 (01) : 19 - 29
  • [6] Photo-electrochemical properties of the TiO2-Pt system in aqueous solutions
    Bak, T
    Nowotny, J
    Rekas, M
    Sorrell, CC
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2002, 27 (01) : 19 - 26
  • [7] Photo-electrochemical hydrogen generation from water using solar energy. Materials-related aspects
    Bak, T
    Nowotny, J
    Rekas, M
    Sorrell, CC
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2002, 27 (10) : 991 - 1022
  • [8] Evaluation of TiO2 coatings obtained using the sol-gel technique on surgical grade type 316L stainless steel in simulated body fluid
    Balamurugan, A
    Kannan, S
    Rajeswari, S
    [J]. MATERIALS LETTERS, 2005, 59 (24-25) : 3138 - 3143
  • [9] PHASE-EQUILIBRIA IN THIN-FILM METALLIZATIONS
    BEYERS, R
    SINCLAIR, R
    THOMAS, ME
    [J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1984, 2 (04): : 781 - 784
  • [10] TiO2 films prepared by ultrasonic spray pyrolysis of nanosize precursor
    Blesic, MD
    Saponjic, ZV
    Nedeljkovic, JM
    Uskokovic, DP
    [J]. MATERIALS LETTERS, 2002, 54 (04) : 298 - 302
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