Fluorescence chemosensor for metal ions using conjugated polymers

被引：0

作者：

Kimura, M ^{[1
]}

Horai, T ^{[1
]}

Hanabusa, K ^{[1
]}

Shirai, H ^{[1
]}

机构：

[1] Shinshu Univ, Fac Text Sci & Technol, Dept Funct Polymer Sci, Ueda, Nagano 386, Japan

来源：

ADVANCED MATERIALS | 1998年 / 10卷 / 06期

关键词：

D O I：

10.1002/(SICI)1521-4095(199804)10:6<459::AID-ADMA459>3.0.CO;2-A

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ability to sense metal ions is a sought-after property in the design of chemical sensors The synthesis of a new metal-ion-sensitive poly(p-phenylenevinylene) that contains terpyridyl ligands in the side chain (see Figure) is reported, and the changes in its fluorescence behavior-quenching or a shift-induced by the addition of several kinds of transition metals are described.

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页码：459 / +

页数：5

相关论文

共 22 条

[1] Synthesis and optical properties of oligo- and poly(2,5-dialkoxy-1,4-para-phenylenevinylene)s [J].

Barashkov, NN ;

Guerrero, DJ ;

Olivos, HJ ;

Ferraris, JP .

SYNTHETIC METALS, 1995, 75 (02) :153-160

[2] MOLECULAR FLUORESCENT SIGNALING WITH FLUOR SPACER RECEPTOR SYSTEMS - APPROACHES TO SENSING AND SWITCHING DEVICES VIA SUPRAMOLECULAR PHOTOPHYSICS [J].

BISSELL, RA ;

DE SILVA, AP ;

GUNARATNE, HQN ;

LYNCH, PLM ;

MAGUIRE, GEM ;

SANDANAYAKE, KRAS .

CHEMICAL SOCIETY REVIEWS, 1992, 21 (03) :187-195

[3] Steric control of directional isomerism in dicopper(I) helicates of asymmetrically substituted 2,2':6',2'':2'',6'''-quaterpyridine derivatives [J].

Constable, EC ;

Heirtzler, F ;

Neuburger, M ;

Zehnder, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (24) :5606-5617

[4] CHEMICAL COMMUNICATION IN WATER USING FLUORESCENT CHEMOSENSORS [J].

CZARNIK, AW .

ACCOUNTS OF CHEMICAL RESEARCH, 1994, 27 (10) :302-308

[5]

GOLL RE, 1994, ADV MAT, V6, P132

[6] EFFICIENT LIGHT-EMITTING-DIODES BASED ON POLYMERS WITH HIGH ELECTRON-AFFINITIES [J].

GREENHAM, NC ;

MORATTI, SC ;

BRADLEY, DDC ;

FRIEND, RH ;

HOLMES, AB .

NATURE, 1993, 365 (6447) :628-630

[7] ELECTROPOLYMERIZATION AND CHARACTERIZATION OF TERPYRIDINYL IRON(II) AND RUTHENIUM(II) COMPLEXES [J].

HANABUSA, K ;

NAKAMURA, A ;

KOYAMA, T ;

SHIRAI, H .

POLYMER INTERNATIONAL, 1994, 35 (03) :231-238

[8] SYNTHESIS AND CHARACTERIZATION OF POLY[2-(2-PHENYLETHENYL)-1,4-PHENYLENE)VINYLENE], POLY[2-METHOXY-5-(2-PHENYLETHENYL)-1,4-PHENYLENE)VINYLENE], AND THEIR COPOLYMERS CONTAINING 1,4-PHENYLENEVINYLENE UNITS [J].

JIN, JI ;

LEE, YH ;

PARK, CK ;

HAN, BK .

MACROMOLECULES, 1994, 27 (19) :5239-5247

[9] SYNTHESIS AND ELECTRICAL-PROPERTIES OF POLY(2-BROMO-5-METHOXY-1,4-PHENYLENEVINYLENE) AND COPOLYMERS [J].

JIN, JI ;

KIM, JC ;

SHIM, HK .

MACROMOLECULES, 1992, 25 (20) :5519-5523

[10]

KUDO Y, 1995, J CHEM SOC CHEM COMM, P1727