(η6-Cyclohepta-1,3,5-triene)(η4-cycloocta-1,5-diene)iron(0) complex as attractive precursor in catalysis

被引：56
作者：
Breschi, C [1 ]
Piparo, L [1 ]
Pertici, P [1 ]
Caporusso, AM [1 ]
Vitulli, G [1 ]
机构：
[1] Univ Pisa, Dipartimento Chim & Chim Ind, CNR Macromol Stereordinate & Otticamente Att, I-56126 Pisa, Italy
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 607卷 / 1-2期
关键词：
iron; hydroformylation; alkyne cyclotrimerisation; cycloolefin complexes; aldehydes; arenes;
D O I：
10.1016/S0022-328X(00)00211-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The catalytic activity of the complex Fe(eta(6)-CHT)(eta(4)-COD), (CHT = 1,3,5-cycloheptatriene; COD = 1,5-cyclooctadiene), 1, has been evaluated in some reference reactions such as the hydroformylation of 1-hexene and styrene and the cyclotrimerisation of a wide range of terminal and internal acetylenes. The title complex has been found to be a convenient catalytic precursor and it resulted more active than other iron catalysts in the investigated reactions. (C) 2000 Elsevier Science S.A. All rights reserved.
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页码：57 / 63
页数：7
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