Fast and Eco-friendly Synthesis of Dipyrromethanes by H2SO4•SiO2 Catalysis under Solvent-free Conditions

被引:17
作者
Zhang Yan [1 ]
Liang Jun [1 ]
Shang Zhicai [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
关键词
dipyrromethane; H2SO4 center dot SiO2; solvent-free; eco-friendly; MESOSUBSTITUTED DIPYRROMETHANES; PORPHYRINS;
D O I
10.1002/cjoc.201090063
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
For the first time, sillica-supported sulfuric acid has been used as a heterogeneous, reusable and efficient catalyst at room temperature to give the corresponding dipyrromethanes in a very short reaction time. The new reaction procedure is simple and solvent is not required.
引用
收藏
页码:259 / 262
页数:4
相关论文
共 16 条
[1]   PICKET-FENCE PORPHYRINS - SYNTHETIC MODELS FOR OXYGEN BINDING HEMOPROTEINS [J].
COLLMAN, JP ;
GAGNE, RR ;
REED, CA ;
HALBERT, TR ;
LANG, G ;
ROBINSON, WT .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1427-1439
[2]   A perspective on four new porphyrin-based functional materials and devices [J].
Drain, CM ;
Hupp, JT ;
Suslick, KS ;
Wasielewski, MR ;
Chen, X .
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2002, 6 (04) :243-258
[3]   New Zn complex derivatives for red OLEDs host materials [J].
Hyun, Ae-Ran ;
Kim, Soo-Kang ;
Kang, In-Nam ;
Park, Jong-Wook ;
Shin, Ji-Young ;
Song, Ok-Keun .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2007, 463 :315-321
[4]   Synthesis, characterization, physicochemical, and photophysical studies of redox switchable NIR dye derived from a ruthenium-dioxolene-porphyrin system [J].
Jose, DA ;
Shukla, AD ;
Kumar, DK ;
Ganguly, B ;
Das, A ;
Ramakrishna, G ;
Palit, DK ;
Ghosh, HN .
INORGANIC CHEMISTRY, 2005, 44 (07) :2414-2425
[5]   ONE-FLASK SYNTHESIS OF MESOSUBSTITUTED DIPYRROMETHANES AND THEIR APPLICATION IN THE SYNTHESIS OF TRANS-SUBSTITUTED PORPHYRIN BUILDING-BLOCKS [J].
LEE, CH ;
LINDSEY, JS .
TETRAHEDRON, 1994, 50 (39) :11427-11440
[6]   ROTHEMUND AND ADLER-LONGO REACTIONS REVISITED - SYNTHESIS OF TETRAPHENYLPORPHYRINS UNDER EQUILIBRIUM CONDITIONS [J].
LINDSEY, JS ;
SCHREIMAN, IC ;
HSU, HC ;
KEARNEY, PC ;
MARGUERETTAZ, AM .
JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (05) :827-836
[7]   Refined synthesis of 5-substituted dipyrromethanes [J].
Littler, BJ ;
Miller, MA ;
Hung, CH ;
Wagner, RW ;
O'Shea, DF ;
Boyle, PD ;
Lindsey, JS .
JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (04) :1391-1396
[8]   Facile synthesis of meso-substituted dipyrromethanes and porphyrins using cation exchange resins [J].
Naik, R ;
Joshi, P ;
Kaiwar, SP ;
Deshpande, RK .
TETRAHEDRON, 2003, 59 (13) :2207-2213
[9]  
Paolesse R., 2000, PORPHYRIN HDB, V2, P201
[10]  
Sessler J.L., 2000, EXPANDED PORPHYRINS, V2, P55